N. M. Kortsenshteyn, L. V. Petrov, A. V. Rudov, A. K. Yastrebov
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Bulk Vapor Condensation upon Intensive Evaporation from Interfacial Surface
An iterative approach has been proposed for analyzing the relation between the processes of intensive evaporation and bulk condensation near an evaporation surface. This approach employs the results of the numerical solution of the Boltzmann kinetic equation for intensive evaporation from an interfacial surface to calculate the kinetics of the bulk condensation near the evaporation surface. It has been shown that, during the lifetime of the supersaturated state of the vapor predicted on the basis of the solution without condensation, the condensation aerosol has sufficient time to be formed. The results obtained indicate that the formation of droplets near the evaporation surface and the thermal effect of the condensation on the vapor parameters must be taken into account when analyzing the intensive evaporation from an interfacial surface.
期刊介绍:
Colloid Journal (Kolloidnyi Zhurnal) is the only journal in Russia that publishes the results of research in the area of chemical science dealing with the disperse state of matter and surface phenomena in disperse systems. The journal covers experimental and theoretical works on a great variety of colloid and surface phenomena: the structure and properties of interfaces; adsorption phenomena and structure of adsorption layers of surfactants; capillary phenomena; wetting films; wetting and spreading; and detergency. The formation of colloid systems, their molecular-kinetic and optical properties, surface forces, interaction of colloidal particles, stabilization, and criteria of stability loss of different disperse systems (lyosols and aerosols, suspensions, emulsions, foams, and micellar systems) are also topics of the journal. Colloid Journal also includes the phenomena of electro- and diffusiophoresis, electro- and thermoosmosis, and capillary and reverse osmosis, i.e., phenomena dealing with the existence of diffusion layers of molecules and ions in the vicinity of the interface.