可持续能源解决方案:利用农业废弃物中的ZnO/SiO2多相催化优化生物柴油生产

IF 2.3 4区 化学 Q3 CHEMISTRY, PHYSICAL Catalysis Letters Pub Date : 2024-12-16 DOI:10.1007/s10562-024-04907-4
Abd Rahman Marlan, Mohammad Nahid Siddiqui, Tawfik A. Saleh, Suriati Eka Putri
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引用次数: 0

摘要

主要由矿物燃料满足的日益增加的全球能源需求已导致严重的环境影响,包括有害污染物的排放和不可再生资源的枯竭。本研究探索了以枣叶灰(DLA)为原料合成绿色多相氧化锌/二氧化硅作为生物柴油生产的创新催化剂,特别是以废食用油(WCO)为原料。WCO是食品工业中普遍存在的副产品,对环境构成重大挑战,但它为可持续能源生产提供了宝贵的机会。本研究的酯交换过程强调了通过关注中间物质来改进产品的附加技术,这对于提高WCO中甘油三酯向生物柴油的转化至关重要,另一方面通过合成催化剂的应用增强了产品,该催化剂具有优异的催化活性和稳定性。该研究还强调了使用多相催化剂相对于传统均相催化剂的优势,包括易于分离、可重复使用和减少对环境的影响。研究结果表明,dla衍生的ZnO/SiO2催化剂不仅提高了生物柴油的产量,而且通过WCO的再利用有助于废物管理,从而减轻其对公共卫生和环境的不利影响。这项工作强调了绿色化学在开发高效、环保催化剂方面的潜力,这些催化剂可以显著推动生物柴油工业的发展。本研究倡导在能源生产中整合可持续实践,强调可再生资源在解决能源可持续性和环境保护的紧迫挑战中的重要性。最终,本研究的几个亮点是在60°C下使用ZnO/SiO2-30将95%以上的WCO转化为生物柴油。图形抽象
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Sustainable Energy Solutions: Optimizing Biodiesel Production through Heterogeneous Catalysis Using ZnO/SiO2 from Agricultural Waste

The escalating global energy demand, predominantly satisfied by fossil fuels, has led to severe environmental repercussions, including the emission of harmful pollutants and the depletion of non-renewable resources. This study explores the synthesis of green heterogeneous ZnO/SiO2 derived from date leaves ash (DLA) as an innovative catalyst for biodiesel production, specifically using waste cooking oil (WCO) as feedstock. WCO, a prevalent byproduct in the food industry, poses significant environmental challenges, yet it offers a valuable opportunity for sustainable energy generation. The transesterification process in this study highlights additional techniques to improve the product by focusing on the intermediate species, which is essential to enhance the conversion of triglycerides in WCO to biodiesel, on the other hand enhanced by the application of the synthesized catalyst, which exhibits superior catalytic activity and stability. The research also highlights the advantages of using heterogeneous catalysts over traditional homogeneous catalysts, including ease of separation, reusability, and reduced environmental impact. The findings demonstrate that the DLA-derived ZnO/SiO2 catalyst not only improves biodiesel yield but also contributes to waste management by repurposing WCO, thereby mitigating its adverse effects on public health and the environment. This work underscores the potential of green chemistry in developing efficient, eco-friendly catalysts that can significantly advance the biodiesel industry. This research advocates the integration of sustainable practices in energy production, emphasizing the importance of renewable resources in addressing the pressing challenges of energy sustainability and environmental protection. Ultimately, several highlights of this research have led to over 95% of WCO being converted to biodiesel using ZnO/SiO2-30 at 60 °C.

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来源期刊
Catalysis Letters
Catalysis Letters 化学-物理化学
CiteScore
5.70
自引率
3.60%
发文量
327
审稿时长
1 months
期刊介绍: Catalysis Letters aim is the rapid publication of outstanding and high-impact original research articles in catalysis. The scope of the journal covers a broad range of topics in all fields of both applied and theoretical catalysis, including heterogeneous, homogeneous and biocatalysis. The high-quality original research articles published in Catalysis Letters are subject to rigorous peer review. Accepted papers are published online first and subsequently in print issues. All contributions must include a graphical abstract. Manuscripts should be written in English and the responsibility lies with the authors to ensure that they are grammatically and linguistically correct. Authors for whom English is not the working language are encouraged to consider using a professional language-editing service before submitting their manuscripts.
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