用于LED应用的MAPbBr3量子点的合成、制造和表征:一个简单的实验室实践

IF 2.5 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Journal of Chemical Education Pub Date : 2024-11-18 DOI:10.1021/acs.jchemed.4c0013910.1021/acs.jchemed.4c00139
Melvia Carinne Mejía Vázquez, Wilson Bernal*, Angel Christian Gómez Téllez, Jaquelina Camacho Cáceres, Diana Marcela Montoya Montoya*, Mauricio Pacio and Hailin Hu, 
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引用次数: 0

摘要

目前,钙钛矿是研究和工业中探索最多的前沿课题之一,因为它们具有特殊的性质,使它们成为广泛应用的候选者,如太阳能电池、传感器和发光二极管(led)。另一方面,教学问题之一是缺乏实验室实践来帮助学生将化学和物理的基本概念与电子器件的制造和表征过程联系起来。在这项工作中,提出了一项实验室实践,为自然科学和工程专业的本科生和研究生展示MAPbBr3钙钛矿量子点(PQDs)的合成和表征及其在led中的应用的简单途径。介绍了用配体辅助再沉淀(LARP)分步合成发光高效pqd的方法。为了避免使用昂贵的高真空系统,采用自旋镀膜方法在环境条件下用共晶场金属作为顶部接触来制造钙钛矿led的活性层。学生对实验实践的积极反馈表明,通过钙钛矿led的制造和表征,有效地学习了概念与应用之间的关系。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Synthesis, Fabrication, and Characterization of MAPbBr3 Quantum Dots for LED Applications: An Easy Laboratory Practice

Currently, perovskites are one of the most explored frontier topics in research and industry due to their exceptional properties that make them a candidate for a wide range of applications, such as solar cells, sensors, and light emitting diodes (LEDs). On the other hand, one of the pedagogical problems is the lack of laboratory practices that can help students to relate the basic concepts of chemistry and physics with the fabrication and characterization process of an electronic device. In this work, a laboratory practice is proposed for undergraduate and postgraduate students in natural sciences and engineering to show an easy route of synthesis and characterization of the MAPbBr3 perovskite quantum dots (PQDs) and their application in LEDs. The step-by-step Ligand-Assisted Re-Precipitation (LARP) method is described for synthesis of luminescent efficient PQDs. A spin-coating method is used to fabricate active layers of perovskite LEDs under ambient conditions with a eutectic field metal as the top contact to avoid the use of expensive high vacuum systems. The positive feedback of the students toward this laboratory practice demonstrates the effective learning on the concept–application relationship through the fabrication and characterization of perovskite LEDs.

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来源期刊
Journal of Chemical Education
Journal of Chemical Education 化学-化学综合
CiteScore
5.60
自引率
50.00%
发文量
465
审稿时长
6.5 months
期刊介绍: The Journal of Chemical Education is the official journal of the Division of Chemical Education of the American Chemical Society, co-published with the American Chemical Society Publications Division. Launched in 1924, the Journal of Chemical Education is the world’s premier chemical education journal. The Journal publishes peer-reviewed articles and related information as a resource to those in the field of chemical education and to those institutions that serve them. JCE typically addresses chemical content, activities, laboratory experiments, instructional methods, and pedagogies. The Journal serves as a means of communication among people across the world who are interested in the teaching and learning of chemistry. This includes instructors of chemistry from middle school through graduate school, professional staff who support these teaching activities, as well as some scientists in commerce, industry, and government.
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