Adsorption of fluorine from lepidolite hydrometallurgy wastewater by aluminum modified zeolite.

Fluoride contamination is a serious environmental problem in lepidolite hydrometallurgy wastewater. The treatment of fluoride-bearing wastewater is challenging because of the presence of coexisting ions including lithium (Li⁺), rubidium (Rb⁺), silicate (SiO₃^2-), sulfate radical (SO₄^2-). However, aluminum-modified zeolite (Al@zeolite) with sufficient hydroxyl groups and high adaptability has unique advantages for eliminating fluoride from lepidolite hydrometallurgy wastewater. Al@zeolite was prepared on natural zeolite by an atmospheric process and then used for the adsorption of fluorine from fluoride-bearing wastewater produced by the lepidolite hydrometallurgy process. The results of material characterization confirmed the successful immobilization of aluminum within the zeolite pores and indicated the formation of zeolite-Al-OH. The zeolite host significantly enhanced the chemical stability of Al@zeolite against pH changes for a wide pH range of 2.0-10.0. The adsorbent had a surface area of 33.46 m²/g and demonstrated excellent capacity and selectivity for fluoride adsorption. Notably, a maximum adsorption of 98.6% was observed at a pH value of 6.0 for a duration of 20 min with a fluoride content of 20 mg/L, and the equilibrium concentration decreased to 0.4 mg/L. The results of fluorine adsorption showed that fluoride uptake onto Al@zeolite agreed well with the pseudo-second-order kinetic model and the Langmuir isotherm model. The reusability of the substance was evaluated for up to eight cycles following consecutive regeneration with 0.2 mol/L AlCl₃. The exhausted Al@zeolite was effectively regenerated through simple alkaline treatment for recycling. The above results verified that Al@zeolite is a new kind of efficient defluoridation adsorbent for lepidolite hydrometallurgy wastewater with practical application prospects.