CoFe2O4纳米颗粒与石墨复合多层热塑性聚氨酯纳米复合材料的优异电磁屏蔽性能

IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Advanced Composites and Hybrid Materials Pub Date : 2024-12-20 DOI:10.1007/s42114-024-01155-3
Nithiya Hanna Wilson,  Anju, Milan Masař, Michal Machovský, David Škoda, Pavel Urbánek, Michal Urbánek, Marek Pöschl, Jarmila Vilčáková, Ivo Kuřitka, Raghvendra Singh Yadav
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引用次数: 0

摘要

本工作介绍了多层聚合物基纳米复合材料的设计和开发,该复合材料通过在热塑性聚氨酯(TPU)基体上结合磁性CoFe2O4纳米颗粒(NPs)和导电石墨,有效地阻挡电磁(EM)辐射。采用声化学方法制备了高纯度的CoFe2O4纳米粒子。采用熔体混合后加压成型的工艺制备了含CoFe2O4 NPs (F-TPU)和石墨(G-TPU)的单层TPU,厚度约为0.8 mm。此外,将三层单层F- tpu或G- tpu以相同的交替方式堆叠,分别形成基于tpu的多层纳米复合材料F/F/F、G/G/G、F/G/F和G/F/G。在8.2 ~ 12.4 GHz的x频段范围内,F/F/F、G/G/G、F/G/F和G/F/G的电磁干扰总屏蔽效能(SET)分别为3.7 dB、33.8 dB、23.9 dB和54.0 dB。这项研究为工程师们提供了一个指南,希望创造出卓越的电磁干扰屏蔽材料,这种材料在雷达安全和信息通信中具有潜在的用途。
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Excellent electromagnetic interference shielding of multi-layered thermoplastic poly-urethane nanocomposites with CoFe2O4 nanoparticles and graphite

This work presents the design and development of multi-layered polymer-based nanocomposites that effectively block electromagnetic (EM) radiation by incorporating magnetic CoFe2O4 nanoparticles (NPs) and conductive graphite on a thermoplastic polyurethane (TPU) matrix. The sonochemical method was employed to produce CoFe2O4 NPs with a high degree of purity. The melt mixing process followed by compression molding was utilized to generate individual layers of TPU containing CoFe2O4 NPs (F-TPU) and graphite (G-TPU) at a thickness of around 0.8 mm. Further, three mono-layers of either F-TPU or G-TPU were stacked in an identical and alternating fashion to create TPU-based multi-layered nanocomposites F/F/F, G/G/G, F/G/F, and G/F/G, respectively. The electromagnetic interference (EMI) total shielding effectiveness (SET) in the X-band frequency range of 8.2–12.4 GHz was investigated and observed to be 3.7 dB, 33.8 dB, 23.9 dB, and 54.0 dB for F/F/F, G/G/G, F/G/F, and G/F/G, respectively. This research offers a guide for engineers looking to create superior EMI shielding materials, which have potential uses in radar security and information communications.

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来源期刊
CiteScore
26.00
自引率
21.40%
发文量
185
期刊介绍: Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.
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