{"title":"生物表面活性剂、Trtions及其混合物在水和水乙醇环境中的吸附和润湿性能。","authors":"Anna Zdziennicka, Bronisław Jańczuk","doi":"10.1016/j.cis.2024.103379","DOIUrl":null,"url":null,"abstract":"<div><div>Adsorption of rhamnolipid (RL) and surfactin (SF) as well as their mixtures with Triton X-100 (TX100) and Triton X-165 (TX165) at the solution-air (S-A), PTFE (polytetrafluoroethylene)-S, PMMA (poly (methyl methacrylate))-S, Q (quartz)-S, PMMA-A, and Q-A as well as their wetting properties regarding the surface tension of the PTFE, PMMA and quartz and its components and parameters were discussed using the literature data. The mutual influence of biosurfactants and Tritons on the S-A, PMMA(quartz)-A and PTFE(PMMA, quartz)-S interfaces tensions was considered in terms of their adsorption at these interfaces for both aqueous and water-ethanol solutions of the biosurfactant mixtures with Tritons. For this purpose there were used different methods on the basis of which the S-A, PMMA(quartz)-A and PTFE(PMMA, quartz)-S interface tensions can be predicted and/or described in the function of concentration and composition of the mixtures. Changes of these interface tensions as a function of concentration and composition of the mixtures were compared to those affected by individual mixture components. In turn, these changes of the interface tension were considered as regards properties of the biosurfactants, Tritons and ethanol layers adsorbed at the S-A, PMMA(quartz)-A and PTFE(PMMA, quartz)-S interfaces. Based on the changes of the contact angle of the aqueous and water-ethanol solutions of the biosurfactants and Tritons as well as biosurfactants mixtures with Tritons on PMMA and quartz as a function of mixture concentration and composition, the changes of the PMMA and quartz surface tension were analyzed using various approaches to the surface and interface tension. The thermodynamic functions change as a results of RL, SF, TX100, TX165, ET as well as the mixtures of RL and SF with Tritons adsorption at different interfaces were also analyzed based on the literature data. These considerations allow to describe and/or predict changes of the interface tension, contact angle of the mixtures as a function of their composition based on these properties of individual mixture components.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"337 ","pages":"Article 103379"},"PeriodicalIF":15.9000,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Adsorption and wetting properties of biosurfactants, Tritons and their mixtures in aqueous and water-ethanol environment\",\"authors\":\"Anna Zdziennicka, Bronisław Jańczuk\",\"doi\":\"10.1016/j.cis.2024.103379\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Adsorption of rhamnolipid (RL) and surfactin (SF) as well as their mixtures with Triton X-100 (TX100) and Triton X-165 (TX165) at the solution-air (S-A), PTFE (polytetrafluoroethylene)-S, PMMA (poly (methyl methacrylate))-S, Q (quartz)-S, PMMA-A, and Q-A as well as their wetting properties regarding the surface tension of the PTFE, PMMA and quartz and its components and parameters were discussed using the literature data. The mutual influence of biosurfactants and Tritons on the S-A, PMMA(quartz)-A and PTFE(PMMA, quartz)-S interfaces tensions was considered in terms of their adsorption at these interfaces for both aqueous and water-ethanol solutions of the biosurfactant mixtures with Tritons. For this purpose there were used different methods on the basis of which the S-A, PMMA(quartz)-A and PTFE(PMMA, quartz)-S interface tensions can be predicted and/or described in the function of concentration and composition of the mixtures. Changes of these interface tensions as a function of concentration and composition of the mixtures were compared to those affected by individual mixture components. In turn, these changes of the interface tension were considered as regards properties of the biosurfactants, Tritons and ethanol layers adsorbed at the S-A, PMMA(quartz)-A and PTFE(PMMA, quartz)-S interfaces. Based on the changes of the contact angle of the aqueous and water-ethanol solutions of the biosurfactants and Tritons as well as biosurfactants mixtures with Tritons on PMMA and quartz as a function of mixture concentration and composition, the changes of the PMMA and quartz surface tension were analyzed using various approaches to the surface and interface tension. The thermodynamic functions change as a results of RL, SF, TX100, TX165, ET as well as the mixtures of RL and SF with Tritons adsorption at different interfaces were also analyzed based on the literature data. These considerations allow to describe and/or predict changes of the interface tension, contact angle of the mixtures as a function of their composition based on these properties of individual mixture components.</div></div>\",\"PeriodicalId\":239,\"journal\":{\"name\":\"Advances in Colloid and Interface Science\",\"volume\":\"337 \",\"pages\":\"Article 103379\"},\"PeriodicalIF\":15.9000,\"publicationDate\":\"2024-12-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advances in Colloid and Interface Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0001868624003026\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advances in Colloid and Interface Science","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0001868624003026","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Adsorption and wetting properties of biosurfactants, Tritons and their mixtures in aqueous and water-ethanol environment
Adsorption of rhamnolipid (RL) and surfactin (SF) as well as their mixtures with Triton X-100 (TX100) and Triton X-165 (TX165) at the solution-air (S-A), PTFE (polytetrafluoroethylene)-S, PMMA (poly (methyl methacrylate))-S, Q (quartz)-S, PMMA-A, and Q-A as well as their wetting properties regarding the surface tension of the PTFE, PMMA and quartz and its components and parameters were discussed using the literature data. The mutual influence of biosurfactants and Tritons on the S-A, PMMA(quartz)-A and PTFE(PMMA, quartz)-S interfaces tensions was considered in terms of their adsorption at these interfaces for both aqueous and water-ethanol solutions of the biosurfactant mixtures with Tritons. For this purpose there were used different methods on the basis of which the S-A, PMMA(quartz)-A and PTFE(PMMA, quartz)-S interface tensions can be predicted and/or described in the function of concentration and composition of the mixtures. Changes of these interface tensions as a function of concentration and composition of the mixtures were compared to those affected by individual mixture components. In turn, these changes of the interface tension were considered as regards properties of the biosurfactants, Tritons and ethanol layers adsorbed at the S-A, PMMA(quartz)-A and PTFE(PMMA, quartz)-S interfaces. Based on the changes of the contact angle of the aqueous and water-ethanol solutions of the biosurfactants and Tritons as well as biosurfactants mixtures with Tritons on PMMA and quartz as a function of mixture concentration and composition, the changes of the PMMA and quartz surface tension were analyzed using various approaches to the surface and interface tension. The thermodynamic functions change as a results of RL, SF, TX100, TX165, ET as well as the mixtures of RL and SF with Tritons adsorption at different interfaces were also analyzed based on the literature data. These considerations allow to describe and/or predict changes of the interface tension, contact angle of the mixtures as a function of their composition based on these properties of individual mixture components.
期刊介绍：
"Advances in Colloid and Interface Science" is an international journal that focuses on experimental and theoretical developments in interfacial and colloidal phenomena. The journal covers a wide range of disciplines including biology, chemistry, physics, and technology.
The journal accepts review articles on any topic within the scope of colloid and interface science. These articles should provide an in-depth analysis of the subject matter, offering a critical review of the current state of the field. The author's informed opinion on the topic should also be included. The manuscript should compare and contrast ideas found in the reviewed literature and address the limitations of these ideas.
Typically, the articles published in this journal are written by recognized experts in the field.
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