C. Casu;M. Buffolo;A. Caria;C. De Santi;N. Trivellin;A. Cester;S. Rampino;M. Bronzoni;M. Mazzer;G. Meneghesso;E. Zanoni;M. Meneghini
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Effect of High Monochromatic Radiation on the Electrical Performance of CIGS Solar Cell
In this article, we investigate the optically induced degradation of Cu(InGa)Se
2
(CIGS) solar cells subjected to monochromatic laser irradiation. The devices under test are bifacial CIGS solar cells, fabricated on fluorine-doped SnO
2
glass substrates. The electrical properties under dark and illumination conditions were characterized before laser exposure. The analysis of the current–voltage characteristics indicated that defect-assisted carrier transport dominates within the space charge region. Continuous laser exposure at constant optical power caused a decrease in open-circuit voltage (
V
oc
). The study of the dark current–voltage curves highlights a change in the saturation current (
IS
) and ideality factor (
n
), whose increment follows a square-root dependence on time. This behavior is attributed to diffusion of Na ions toward the junction. Conversely, the
V
oc
decay (which is correlated with the turn-
on
voltage decrease in dark
I–V
curve) is ascribed to a light-induced defect generation that enhances leakage current at the CdS/CIGS interface.
期刊介绍:
The IEEE Journal of Photovoltaics is a peer-reviewed, archival publication reporting original and significant research results that advance the field of photovoltaics (PV). The PV field is diverse in its science base ranging from semiconductor and PV device physics to optics and the materials sciences. The journal publishes articles that connect this science base to PV science and technology. The intent is to publish original research results that are of primary interest to the photovoltaic specialist. The scope of the IEEE J. Photovoltaics incorporates: fundamentals and new concepts of PV conversion, including those based on nanostructured materials, low-dimensional physics, multiple charge generation, up/down converters, thermophotovoltaics, hot-carrier effects, plasmonics, metamorphic materials, luminescent concentrators, and rectennas; Si-based PV, including new cell designs, crystalline and non-crystalline Si, passivation, characterization and Si crystal growth; polycrystalline, amorphous and crystalline thin-film solar cell materials, including PV structures and solar cells based on II-VI, chalcopyrite, Si and other thin film absorbers; III-V PV materials, heterostructures, multijunction devices and concentrator PV; optics for light trapping, reflection control and concentration; organic PV including polymer, hybrid and dye sensitized solar cells; space PV including cell materials and PV devices, defects and reliability, environmental effects and protective materials; PV modeling and characterization methods; and other aspects of PV, including modules, power conditioning, inverters, balance-of-systems components, monitoring, analyses and simulations, and supporting PV module standards and measurements. Tutorial and review papers on these subjects are also published and occasionally special issues are published to treat particular areas in more depth and breadth.