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IEEE Journal of Photovoltaics Publication Information IEEE光电杂志出版信息
IF 2.6 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-22 DOI: 10.1109/JPHOTOV.2025.3642491
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引用次数: 0
Call for Papers for a Special Issue of IEEE Transactions on Electron Devices on “Ultrawide Band Gap Semiconductor Device for RF, Power and Optoelectronic Applications” IEEE电子器件学报特刊“用于射频、功率和光电子应用的超宽带隙半导体器件”征文
IF 2.6 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-22 DOI: 10.1109/JPHOTOV.2025.3642585
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引用次数: 0
IEEE Journal of Photovoltaics Information for Authors IEEE光电期刊,作者信息
IF 2.6 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-22 DOI: 10.1109/JPHOTOV.2025.3642495
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引用次数: 0
Advancements in Self-Assembled Monolayers for Perovskite Solar Cells 钙钛矿太阳能电池自组装单层膜的研究进展
IF 2.6 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-08 DOI: 10.1109/JPHOTOV.2025.3627664
Nur Najiha Binti Ahmad Rasid;Nur Wardina Syahirah Binti Mohamad Fadil;Peng Gao;Abd. Rashid Bin Mohd Yusoff
Self-assembled monolayers (SAMs) are well known as a promising strategy for enhancing the efficiency, stability, and interfacial properties of perovskite solar cells (PSCs). These molecular layers, typically formed through surface binding between electrode surfaces, enable fine-tuning of surface energetics, promote uniform film formation, and suppress interfacial recombination. Lead (Pb)-halide perovskite systems are renowned for their remarkable power conversion efficiencies, with SAMs playing a crucial role in optimizing charge extraction and mitigating degradation pathways. This review explores recent advancements in SAM-functionalized interfaces, particularly focusing on their chemical structure, anchoring groups, electronic alignment, and compatibility with perovskite and charge transport layers. We also highlight the comparative performance of SAM-modified PSCs, discuss current challenges, and suggest future directions for material innovation and device engineering.
自组装单层膜(SAMs)被认为是提高钙钛矿太阳能电池(PSCs)效率、稳定性和界面性能的一种很有前途的策略。这些分子层通常是通过电极表面之间的表面结合形成的,可以实现表面能量的微调,促进均匀的薄膜形成,并抑制界面重组。铅(Pb)卤化物钙钛矿系统以其卓越的功率转换效率而闻名,其中sam在优化电荷提取和减轻降解途径方面发挥着至关重要的作用。本文综述了sam功能化界面的最新进展,特别关注它们的化学结构、锚定基团、电子排列以及与钙钛矿和电荷传输层的兼容性。我们还强调了sam改性PSCs的比较性能,讨论了当前的挑战,并提出了材料创新和器件工程的未来方向。
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引用次数: 0
Understanding and Reducing the Risk of Extreme Photovoltaic Degradation 理解和减少极端光伏退化的风险
IF 2.6 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-04 DOI: 10.1109/JPHOTOV.2025.3627676
Y. Tang;S. Poddar;M. Kay;F. E. Rougieux
A small number of photovoltaic modules degrade far more rapidly than average, creating a “long tail” in degradation rate distribution that poses a critical challenge to the reliability and financial viability of solar projects. This study investigates the factors contributing to this phenomenon by analyzing a large global dataset from the National Renewable Energy Laboratory. Our analysis reveals that the long tail is an intrinsic and composite feature of module degradation, not merely a statistical consequence of combining different climates. We identify at least three distinct pathways that could contribute to its formation. The first is accelerated degradation driven by strong statistical associations between different degradation modes, where the interplay of mechanisms appears to be a primary contributor of the most severely degraded modules. The second is rapid early-life failure (infant mortality), which populates the tail with modules likely containing initial manufacturing or material defects. The third is failure of individual latent defects, such as solder fatigue or cell cracks, which can cause sudden severe performance loss at random points in a module's life. Based on our results, we suggest that efforts should be made to understand and mitigate the interaction between associated degradation modes. For instance, the careful selection of key components, such as backsheet, is crucial as it could initiate multiple pathways of degradation.
少数光伏组件的降解速度远快于平均水平,在降解率分布上形成“长尾”,对太阳能项目的可靠性和财务可行性构成重大挑战。本研究通过分析国家可再生能源实验室的大型全球数据集,调查了导致这一现象的因素。我们的分析表明,长尾是模块退化的内在和复合特征,而不仅仅是组合不同气候的统计结果。我们确定了至少三种不同的途径可能有助于它的形成。第一种是由不同退化模式之间的强大统计关联驱动的加速退化,其中机制的相互作用似乎是最严重退化模式的主要因素。第二种是生命早期的快速失效(婴儿死亡),它在尾部填充可能包含初始制造或材料缺陷的模块。第三种是单个潜在缺陷的失效,如焊料疲劳或电池裂纹,这可能在模块寿命的随机点导致突然严重的性能损失。基于我们的研究结果,我们建议应该努力理解和减轻相关降解模式之间的相互作用。例如,仔细选择关键部件,如背板,是至关重要的,因为它可以启动多种降解途径。
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引用次数: 0
Pyrolyzer Assisted Vapor Transport Deposition of Antimony-Doped Cadmium Telluride 热裂解辅助气相输运沉积掺锑碲化镉
IF 2.6 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-04 DOI: 10.1109/JPHOTOV.2025.3633076
Bin Du;Gregory A. Manoukian;Harvey Guthrey;Aayush Nahar;António J. N. Oliveira;Kevin D. Dobson;Brian McCandless;Aaron Arehart;Jason B. Baxter;William N. Shafarman
In this study, we developed a new method for in situ Sb doping of CdTe thin films combining vapor transport deposition with a Group V pyrolyzer to address Sb doping concentration and doping efficiency. The Sb doped CdSeTe (CdSeTe:Sb) films were deposited in solar cell structures under variations of Sb dopant source heater, vapor pyrolyzer temperature, and Cd vapor excess. Results indicate that although these parameters do not affect the CdTe morphology or crystal structure, they critically influence doping efficiency and trap concentration. Capacitance–voltage measurements show that a higher dopant heater (TD) or pyrolyzer (TP) temperature leads to higher net carrier concentration, achieving a net carrier concentration of 1016 cm−3 and 20% doping efficiency with a TD/TP combination of 600 °C/1100 °C. By tuning the Cd/Sb flux ratio during CdSeTe:Sb deposition, the lowest defect concentration is achieved at Cd/Sb of 1.4:1, which produced the best VOC CdSeTe:Sb cell. This demonstrates a path to produce high net carrier concentration polycrystalline CdTe thin film with a low concentration of dopant-induced defects.
在本研究中,我们开发了一种将气相输运沉积与V族热解相结合的CdTe薄膜原位掺杂Sb的新方法,以解决Sb掺杂浓度和掺杂效率的问题。在不同的Sb掺杂源加热器、蒸汽热解器温度和Cd蒸气过量条件下,在太阳能电池结构中沉积了Sb掺杂CdSeTe (CdSeTe:Sb)薄膜。结果表明,虽然这些参数不影响CdTe的形貌和晶体结构,但它们对掺杂效率和陷阱浓度有重要影响。电容电压测量表明,较高的掺杂加热器(TD)或热解器(TP)温度导致更高的净载流子浓度,在TD/TP组合温度为600°C/1100°C时,净载流子浓度达到1016 cm−3,掺杂效率为20%。通过调整CdSeTe:Sb沉积过程中Cd/Sb的通量比,在Cd/Sb为1.4:1时达到了最低的缺陷浓度,得到了VOC最好的CdSeTe:Sb电池。这证明了一种生产高净载流子浓度的多晶碲化镉薄膜和低浓度掺杂诱导缺陷的途径。
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引用次数: 0
New Rapid Method for Optical Nondestructive Determination of the Degree of Crosslinking of PV Module Encapsulants 光学无损快速测定光伏组件封装剂交联度的新方法
IF 2.6 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-01 DOI: 10.1109/JPHOTOV.2025.3635341
Gernot Oreski;Márton Bredács;Sonja Feldbacher;Petra Christöfl;Jutta Geier;Chiara Barretta;Christian Camus;Enno Malguth;Adrian
The degree of crosslinking in encapsulants is a critical parameter in photovoltaic (PV) module production, significantly influencing module performance and reliability. Despite its importance, the industry-standard Soxhlet extraction method for assessing crosslinking is offline, time-intensive, and unsuitable to implement for real-time process monitoring. This study explores the application of near-infrared (NIR) spectroscopy as a faster, nondestructive alternative for determining encapsulant crosslinking. Test laminates using an ethylene vinyl acetate (EVA) encapsulant with varying crosslinking times were analyzed using both Soxhlet extraction and NIR spectroscopy. The NIR spectra were processed using multivariate data analysis methods for qualitative classification and quantitative prediction. The classification model demonstrated clear separation between encapsulants with high and low degrees of crosslinking. The prediction model achieved a high accuracy prediction of the degree of crosslinking. These findings highlight the potential of NIR spectroscopy for rapid, inline classification and quantification of encapsulant crosslinking. Future work will expand the calibration models to include polyolefin (POE) and co-extruded POE–EVA encapsulants to verify robustness across different chemistries, and optimizing measurement setups to accommodate double-glass module designs.
封装剂的交联程度是光伏组件生产中的一个关键参数,对组件的性能和可靠性有重要影响。尽管它很重要,但用于评估交联的行业标准索氏提取方法是离线的,耗时的,并且不适合实现实时过程监控。本研究探索了近红外(NIR)光谱的应用,作为一种更快、无损的替代方法来测定封装剂的交联。采用不同交联时间的乙烯醋酸乙烯(EVA)封装材料对层压板进行了索氏提取和近红外光谱分析。采用多元数据分析方法对近红外光谱进行定性分类和定量预测。分类模型表明,高交联度和低交联度的封装剂之间有明显的分离。该预测模型实现了对交联度的高精度预测。这些发现突出了近红外光谱快速、在线分类和定量封装剂交联的潜力。未来的工作将扩展校准模型,包括聚烯烃(POE)和共挤POE - eva密封剂,以验证不同化学物质的稳健性,并优化测量设置以适应双玻璃模块设计。
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引用次数: 0
Quantum Dot Concentration-Mediated Synergistic Optimization of Absorber Thickness and Interface Defects in Infrared Quantum Dot/Perovskite Nanorod Array Solar Cells 红外量子点/钙钛矿纳米棒阵列太阳能电池吸收剂厚度和界面缺陷的量子点浓度协同优化
IF 2.6 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-11-27 DOI: 10.1109/JPHOTOV.2025.3633056
Luming Zhou;Yahong Wang;Peng Ye;Junying Yu;Lin He;Chunlin Fu
The thickness of the light-absorbing layer and interface defects are the key factors affecting the photovoltaic performance of perovskite solar cells. In this article, aiming at the problem of carrier recombination caused by the thickness of the light-absorbing layer and interface defects in infrared quantum dot/perovskite composite nanorod arrays, a strategy of synergistically optimizing the thickness of the quantum dot absorption layer and interface passivation performance by adjusting the concentration of PbS-PbI2 quantum dots is proposed. Experimental results indicate that quantum dot concentration significantly influences light-absorbing layer properties. At 40 mg/mL, the absorber layer thickness increases to 27.5 nm, interface defect density decreases, carrier transport efficiency improves, near-infrared light absorption enhances, and optimal photovoltaic performance is achieved (Jsc = 14.72 mA/cm2, PCE = 6.65%). When concentration exceeds 40 mg/mL, quantum dot agglomeration causes absorber thickness to sharply decrease to 20.5 nm, interface defect density increases, and both light absorption efficiency and photovoltaic performance decline (Jsc = 11.58 mA/cm2, PCE = 4.41%). Through XRD, SEM, and EIS characterization, it was found that at a concentration of 40 mg/mL, a moderate thickness of the light-absorbing layer improves the near-infrared light capture ability, effectively passivates the interface defects through the Pb2+-I- coordination bond, and optimizes the perovskite crystal quality and carrier kinetics. This article reveals the regulation of quantum dot concentration on device performance through the synergistic mechanism of “absorber layer thickness and interface defect-light absorption-photovoltaic performance,” which provides guidance for efficient interface engineering of the perovskite/quantum dot composite system.
光吸收层厚度和界面缺陷是影响钙钛矿太阳能电池光伏性能的关键因素。本文针对红外量子点/钙钛矿复合纳米棒阵列中由于吸光层厚度和界面缺陷导致的载流子复合问题,提出了一种通过调整PbS-PbI2量子点浓度来协同优化量子点吸收层厚度和界面钝化性能的策略。实验结果表明,量子点浓度对吸光层性能有显著影响。在40 mg/mL时,吸收层厚度增加到27.5 nm,界面缺陷密度降低,载流子输运效率提高,近红外光吸收增强,光伏性能达到最佳(Jsc = 14.72 mA/cm2, PCE = 6.65%)。当浓度超过40 mg/mL时,量子点团聚导致吸收剂厚度急剧减小至20.5 nm,界面缺陷密度增大,光吸收效率和光伏性能均下降(Jsc = 11.58 mA/cm2, PCE = 4.41%)。通过XRD、SEM和EIS表征发现,在浓度为40 mg/mL时,适度厚度的吸光层提高了近红外光捕获能力,通过Pb2+- i -配位键有效钝化界面缺陷,优化了钙钛矿晶体质量和载流子动力学。本文通过“吸收层厚度与界面缺陷-光吸收-光伏性能”的协同机制揭示了量子点浓度对器件性能的调控作用,为钙钛矿/量子点复合体系的高效界面工程提供了指导。
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引用次数: 0
High-Throughput In-Line Deposition of Silicon Oxide for Polycrystalline Silicon Passivating Contacts 用于多晶硅钝化触点的高通量在线沉积氧化硅
IF 2.6 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-11-24 DOI: 10.1109/JPHOTOV.2025.3622321
Zachary B. Leuty;William J. Weigand;Jorge Ochoa;Joe V. Carpenter;Mariana I. Bertoni;Zachary C. Holman
Polycrystalline silicon passivating contacts rely on an ultrathin (1–2 nm) silicon oxide layer to minimize recombination at the wafer/oxide interface and regulate dopant diffusion. Traditionally formed by thermal or chemical oxidation, this oxide is herein replaced by silicon oxide deposited via aerosol impact-driven assembly (AIDA), enabling high wafer-per-hour throughput and precise thickness control. In this study, we show that AIDA coatings conformally cover planar or textured substrates and achieve a SiOx/poly-Si(n) structure with an implied open-circuit voltage (iVoc = 726 mV) and contact saturation current density (J0 = 8.8 fA/cm2). Furthermore, annealing AIDA SiOx films at elevated temperatures desorbs hydroxyl groups while the stoichiometry transitions toward SiO2, improving passivation quality. Together, these results highlight AIDA’s potential for scalable, high-throughput manufacturing of advanced passivating contacts, offering a cost-effective alternative to conventional low-pressure chemical vapor deposition and plasma-enhanced chemical vapor deposition-based silicon and oxide processes.
多晶硅钝化触点依靠超薄(1 - 2nm)氧化硅层来减少晶圆/氧化物界面的复合并调节掺杂物的扩散。传统上,这种氧化物是通过热氧化或化学氧化形成的,而在这里,这种氧化物被通过气溶胶冲击驱动组装(AIDA)沉积的氧化硅所取代,从而实现了每小时高晶圆吞吐量和精确的厚度控制。在这项研究中,我们发现AIDA涂层可以保形覆盖平面或纹理基底,并实现SiOx/poly-Si(n)结构,具有隐含开路电压(iVoc = 726 mV)和接触饱和电流密度(J0 = 8.8 fA/cm2)。此外,在高温下退火AIDA SiOx薄膜,当化学计量向SiO2转变时,羟基脱吸,提高了钝化质量。总之,这些结果突出了AIDA在可扩展、高通量制造先进钝化触点方面的潜力,为传统的低压化学气相沉积和等离子体增强化学气相沉积硅和氧化物工艺提供了一种具有成本效益的替代方案。
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引用次数: 0
Uniform Mechanical Loading Can Test for Nonuniform Loading Durability 均匀机械加载罐非均匀加载耐久性试验
IF 2.6 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-11-17 DOI: 10.1109/JPHOTOV.2025.3625245
Nick Bosco;Martin Springer
In this work, we present a method to evaluate the equivalency between any module mechanical loading conditions. The method is developed to address the specific failure mode of glass fracture and is based on Weibull analysis and weakest link theory. It considers the varying stress profile across the module to calculate the probability of glass fracture, which is used as the metric of equivalency. An idealized nonuniform loading scheme is employed to demonstrate the method and introduce the concept of the equivalent uniform load factor: a factor applied to the maximum pressure of the nonuniform load to obtain the equivalent uniform load value. It is demonstrated that this factor is less than unity for all nonuniform load cases considered, including snow and various characters of wind loading. These significant results suggest that uniform loading may be reliably, and practically, employed to evaluate photovoltaic module glass for nonuniform loading durability.
在这项工作中,我们提出了一种评估任何模块机械加载条件之间等效性的方法。该方法是基于威布尔分析和最薄弱环节理论,针对玻璃断裂的特定破坏模式而开发的。它考虑了整个模块的变化应力分布来计算玻璃破裂的概率,并将其作为等效度量。采用一种理想的非均布荷载方案来演示该方法,并引入等效均布荷载因子的概念,即对非均布荷载的最大压力施加的因子,以获得等效均布荷载值。结果表明,在所有考虑非均匀荷载的情况下,包括雪荷载和风荷载的各种特性,该因子都小于一。这些显著的结果表明,均匀载荷可以可靠和实用地用于评估光伏组件玻璃的非均匀载荷耐久性。
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引用次数: 0
期刊
IEEE Journal of Photovoltaics
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