{"title":"丙烷/空气混合物在瞬态高温下的爆炸危险性","authors":"Hanzheng Gong, Huimin Liang, Qi Zhang","doi":"10.1007/s10973-024-13817-x","DOIUrl":null,"url":null,"abstract":"<div><p>For the safe storage of abandoned liquefied fuel tanks, studying the critical temperature threshold for propane tank explosions under transient high-temperature loading is crucial. Transient high temperatures may cause the combustion of residual combustible gases inside abandoned liquefied gas tanks, leading to casualties and property damage. In this paper, numerical simulation methods are employed to investigate the critical temperature exposure time, temperature propagation process and explosion characteristic parameters of propane tanks (propane volume fraction is 4%) under different transient high-temperature loads. The results suggest that propane ignition is influenced by two factors: thermal decomposition and heat conduction. When the high-temperature intensity is fixed, as the exposure time increases, the ignition starting point of propane inside the tank gradually moves toward the upper corners of the tank's sides. At external wall temperatures of 800 K, 1000 K, 1200 K and 1400 K, as the temperature intensity increases, heat propagates more rapidly through the tank's shell. This shortens the explosion delay time and increases the explosion hazard.</p></div>","PeriodicalId":678,"journal":{"name":"Journal of Thermal Analysis and Calorimetry","volume":"149 24","pages":"14925 - 14942"},"PeriodicalIF":3.0000,"publicationDate":"2024-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Explosion hazard of propane/air mixture in tank under transient high temperature\",\"authors\":\"Hanzheng Gong, Huimin Liang, Qi Zhang\",\"doi\":\"10.1007/s10973-024-13817-x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>For the safe storage of abandoned liquefied fuel tanks, studying the critical temperature threshold for propane tank explosions under transient high-temperature loading is crucial. Transient high temperatures may cause the combustion of residual combustible gases inside abandoned liquefied gas tanks, leading to casualties and property damage. In this paper, numerical simulation methods are employed to investigate the critical temperature exposure time, temperature propagation process and explosion characteristic parameters of propane tanks (propane volume fraction is 4%) under different transient high-temperature loads. The results suggest that propane ignition is influenced by two factors: thermal decomposition and heat conduction. When the high-temperature intensity is fixed, as the exposure time increases, the ignition starting point of propane inside the tank gradually moves toward the upper corners of the tank's sides. At external wall temperatures of 800 K, 1000 K, 1200 K and 1400 K, as the temperature intensity increases, heat propagates more rapidly through the tank's shell. This shortens the explosion delay time and increases the explosion hazard.</p></div>\",\"PeriodicalId\":678,\"journal\":{\"name\":\"Journal of Thermal Analysis and Calorimetry\",\"volume\":\"149 24\",\"pages\":\"14925 - 14942\"},\"PeriodicalIF\":3.0000,\"publicationDate\":\"2024-11-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Thermal Analysis and Calorimetry\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10973-024-13817-x\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Thermal Analysis and Calorimetry","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s10973-024-13817-x","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Explosion hazard of propane/air mixture in tank under transient high temperature
For the safe storage of abandoned liquefied fuel tanks, studying the critical temperature threshold for propane tank explosions under transient high-temperature loading is crucial. Transient high temperatures may cause the combustion of residual combustible gases inside abandoned liquefied gas tanks, leading to casualties and property damage. In this paper, numerical simulation methods are employed to investigate the critical temperature exposure time, temperature propagation process and explosion characteristic parameters of propane tanks (propane volume fraction is 4%) under different transient high-temperature loads. The results suggest that propane ignition is influenced by two factors: thermal decomposition and heat conduction. When the high-temperature intensity is fixed, as the exposure time increases, the ignition starting point of propane inside the tank gradually moves toward the upper corners of the tank's sides. At external wall temperatures of 800 K, 1000 K, 1200 K and 1400 K, as the temperature intensity increases, heat propagates more rapidly through the tank's shell. This shortens the explosion delay time and increases the explosion hazard.
期刊介绍:
Journal of Thermal Analysis and Calorimetry is a fully peer reviewed journal publishing high quality papers covering all aspects of thermal analysis, calorimetry, and experimental thermodynamics. The journal publishes regular and special issues in twelve issues every year. The following types of papers are published: Original Research Papers, Short Communications, Reviews, Modern Instruments, Events and Book reviews.
The subjects covered are: thermogravimetry, derivative thermogravimetry, differential thermal analysis, thermodilatometry, differential scanning calorimetry of all types, non-scanning calorimetry of all types, thermometry, evolved gas analysis, thermomechanical analysis, emanation thermal analysis, thermal conductivity, multiple techniques, and miscellaneous thermal methods (including the combination of the thermal method with various instrumental techniques), theory and instrumentation for thermal analysis and calorimetry.