{"title":"C-S-H种子对高碳稻壳灰混合硅酸盐水泥水化反应的影响","authors":"Guilherme Durigon Cocco, Amanda Pereira Vieira, Eduardo Moraes Rego Fairbairn, Oscar Mendoza Reales","doi":"10.1007/s10973-024-13855-5","DOIUrl":null,"url":null,"abstract":"<div><p>The use of Calcium silicate hydrate (C–S–H) seeds is a promising solution to accelerate the hydration kinetics of Portland cement mixtures blended containing supplementary cementitious materials (SCM) with a low initial reactivity. However, the interaction mechanisms between C–S–H seeds and alternative SCM, such as Rice husk ash (RHA), are still not fully understood. In this paper, pastes with three levels of Portland cement replacement (10, 20, and 30% by volume of cement) by a high-carbon content RHA were analyzed, with and without the addition of 3% C–S–H seeds. The hydration process and the mechanical performance of the pastes were evaluated through isothermal calorimetry for seven days, thermogravimetric analysis, and compressive strength after 1, 7, and 28 days. The results showed that the C–S–H seeds increased Portlandite consumption during the first hours of the hydration process and enhanced compressive strength after one day of curing. These finds suggested that the use of C–S–H seeds could eliminate the delay in the hydration process and strength development during the initial hours caused by the high-carbon content and low reactivity of RHA.</p></div>","PeriodicalId":678,"journal":{"name":"Journal of Thermal Analysis and Calorimetry","volume":"149 24","pages":"14663 - 14675"},"PeriodicalIF":3.0000,"publicationDate":"2024-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of C–S–H seeds on the hydration reaction of Portland cement matrices blended with a high-carbon content rice husk ash\",\"authors\":\"Guilherme Durigon Cocco, Amanda Pereira Vieira, Eduardo Moraes Rego Fairbairn, Oscar Mendoza Reales\",\"doi\":\"10.1007/s10973-024-13855-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The use of Calcium silicate hydrate (C–S–H) seeds is a promising solution to accelerate the hydration kinetics of Portland cement mixtures blended containing supplementary cementitious materials (SCM) with a low initial reactivity. However, the interaction mechanisms between C–S–H seeds and alternative SCM, such as Rice husk ash (RHA), are still not fully understood. In this paper, pastes with three levels of Portland cement replacement (10, 20, and 30% by volume of cement) by a high-carbon content RHA were analyzed, with and without the addition of 3% C–S–H seeds. The hydration process and the mechanical performance of the pastes were evaluated through isothermal calorimetry for seven days, thermogravimetric analysis, and compressive strength after 1, 7, and 28 days. The results showed that the C–S–H seeds increased Portlandite consumption during the first hours of the hydration process and enhanced compressive strength after one day of curing. These finds suggested that the use of C–S–H seeds could eliminate the delay in the hydration process and strength development during the initial hours caused by the high-carbon content and low reactivity of RHA.</p></div>\",\"PeriodicalId\":678,\"journal\":{\"name\":\"Journal of Thermal Analysis and Calorimetry\",\"volume\":\"149 24\",\"pages\":\"14663 - 14675\"},\"PeriodicalIF\":3.0000,\"publicationDate\":\"2024-12-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Thermal Analysis and Calorimetry\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10973-024-13855-5\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Thermal Analysis and Calorimetry","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s10973-024-13855-5","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Effect of C–S–H seeds on the hydration reaction of Portland cement matrices blended with a high-carbon content rice husk ash
The use of Calcium silicate hydrate (C–S–H) seeds is a promising solution to accelerate the hydration kinetics of Portland cement mixtures blended containing supplementary cementitious materials (SCM) with a low initial reactivity. However, the interaction mechanisms between C–S–H seeds and alternative SCM, such as Rice husk ash (RHA), are still not fully understood. In this paper, pastes with three levels of Portland cement replacement (10, 20, and 30% by volume of cement) by a high-carbon content RHA were analyzed, with and without the addition of 3% C–S–H seeds. The hydration process and the mechanical performance of the pastes were evaluated through isothermal calorimetry for seven days, thermogravimetric analysis, and compressive strength after 1, 7, and 28 days. The results showed that the C–S–H seeds increased Portlandite consumption during the first hours of the hydration process and enhanced compressive strength after one day of curing. These finds suggested that the use of C–S–H seeds could eliminate the delay in the hydration process and strength development during the initial hours caused by the high-carbon content and low reactivity of RHA.
期刊介绍:
Journal of Thermal Analysis and Calorimetry is a fully peer reviewed journal publishing high quality papers covering all aspects of thermal analysis, calorimetry, and experimental thermodynamics. The journal publishes regular and special issues in twelve issues every year. The following types of papers are published: Original Research Papers, Short Communications, Reviews, Modern Instruments, Events and Book reviews.
The subjects covered are: thermogravimetry, derivative thermogravimetry, differential thermal analysis, thermodilatometry, differential scanning calorimetry of all types, non-scanning calorimetry of all types, thermometry, evolved gas analysis, thermomechanical analysis, emanation thermal analysis, thermal conductivity, multiple techniques, and miscellaneous thermal methods (including the combination of the thermal method with various instrumental techniques), theory and instrumentation for thermal analysis and calorimetry.