C-S-H种子对高碳稻壳灰混合硅酸盐水泥水化反应的影响

IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Journal of Thermal Analysis and Calorimetry Pub Date : 2024-12-02 DOI:10.1007/s10973-024-13855-5
Guilherme Durigon Cocco, Amanda Pereira Vieira, Eduardo Moraes Rego Fairbairn, Oscar Mendoza Reales
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引用次数: 0

摘要

水合硅酸钙(C-S-H)种子是一种很有前途的解决方案,可以加速硅酸盐水泥混合料的水化动力学,该混合料含有低初始反应活性的补充胶凝材料(SCM)。然而,C-S-H种子与替代SCM(如稻壳灰)之间的相互作用机制仍未完全了解。本文分析了用高碳含量RHA替代波特兰水泥(水泥体积比为10%、20%和30%)三种水平的膏体,分别添加和不添加3% C-S-H种子。通过7天等温量热法、热重分析和1、7、28天的抗压强度来评价膏体的水化过程和力学性能。结果表明,C-S-H种子在水化过程的头几个小时内增加了波特兰石的消耗,养护1天后抗压强度有所提高。这些结果表明,使用C-S-H种子可以消除由于RHA的高碳含量和低反应性而导致的水化过程和强度发展的延迟。
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Effect of C–S–H seeds on the hydration reaction of Portland cement matrices blended with a high-carbon content rice husk ash

The use of Calcium silicate hydrate (C–S–H) seeds is a promising solution to accelerate the hydration kinetics of Portland cement mixtures blended containing supplementary cementitious materials (SCM) with a low initial reactivity. However, the interaction mechanisms between C–S–H seeds and alternative SCM, such as Rice husk ash (RHA), are still not fully understood. In this paper, pastes with three levels of Portland cement replacement (10, 20, and 30% by volume of cement) by a high-carbon content RHA were analyzed, with and without the addition of 3% C–S–H seeds. The hydration process and the mechanical performance of the pastes were evaluated through isothermal calorimetry for seven days, thermogravimetric analysis, and compressive strength after 1, 7, and 28 days. The results showed that the C–S–H seeds increased Portlandite consumption during the first hours of the hydration process and enhanced compressive strength after one day of curing. These finds suggested that the use of C–S–H seeds could eliminate the delay in the hydration process and strength development during the initial hours caused by the high-carbon content and low reactivity of RHA.

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来源期刊
CiteScore
8.50
自引率
9.10%
发文量
577
审稿时长
3.8 months
期刊介绍: Journal of Thermal Analysis and Calorimetry is a fully peer reviewed journal publishing high quality papers covering all aspects of thermal analysis, calorimetry, and experimental thermodynamics. The journal publishes regular and special issues in twelve issues every year. The following types of papers are published: Original Research Papers, Short Communications, Reviews, Modern Instruments, Events and Book reviews. The subjects covered are: thermogravimetry, derivative thermogravimetry, differential thermal analysis, thermodilatometry, differential scanning calorimetry of all types, non-scanning calorimetry of all types, thermometry, evolved gas analysis, thermomechanical analysis, emanation thermal analysis, thermal conductivity, multiple techniques, and miscellaneous thermal methods (including the combination of the thermal method with various instrumental techniques), theory and instrumentation for thermal analysis and calorimetry.
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