{"title":"可控交联制备高强度、高透明度、高抗冲击聚氨酯弹性体及其应用","authors":"Siqi Zhan, Hongyan Liu, Yanyan Bo, Ruize Yuan, Yuting Zhang, Dongxiu Zhang, Huimin Yang, Xin Tian, Shiwei Wang, Mingyao Zhang","doi":"10.1016/j.polymer.2024.128002","DOIUrl":null,"url":null,"abstract":"<div><div>In recent years, polyurethane elastomer has been widespread used in automotive, aerospace, and other fields depending on its wide range of adjustable properties, both high elasticity of rubber and plastic rigidity. Its high transparency and high strength have attracted increasing attention, especially in the application of laminated safety glass. In this work, an aliphatic polyurethane film with superior dynamic impact resistance, optical and mechanical properties were successfully obtained by controlling the cross-linking agent and cross-linking degree. The effects of different cross-linking point structures on the structure and properties of aliphatic polyurethane were revealed. The optimal bonding strength and tensile strength can reach 1.7 MPa and 43 MPa, which are 170 % and 301 % higher than those of polyurethane, respectively. The transmittance of the aliphatic polyurethane can reach 80 %. Extremely superior impact resistance of the laminated safety glass based on the aliphatic polyurethane have been verified. The ultimate bearing capacity was 14 times of unmodified polyurethane. It will have huge application potential in the fields of aerospace, construction and automotive.</div></div>","PeriodicalId":405,"journal":{"name":"Polymer","volume":"318 ","pages":"Article 128002"},"PeriodicalIF":4.1000,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation and application of high strength, high transparency, and high impact resistance polyurethane elastomers by controlled cross-linking\",\"authors\":\"Siqi Zhan, Hongyan Liu, Yanyan Bo, Ruize Yuan, Yuting Zhang, Dongxiu Zhang, Huimin Yang, Xin Tian, Shiwei Wang, Mingyao Zhang\",\"doi\":\"10.1016/j.polymer.2024.128002\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In recent years, polyurethane elastomer has been widespread used in automotive, aerospace, and other fields depending on its wide range of adjustable properties, both high elasticity of rubber and plastic rigidity. Its high transparency and high strength have attracted increasing attention, especially in the application of laminated safety glass. In this work, an aliphatic polyurethane film with superior dynamic impact resistance, optical and mechanical properties were successfully obtained by controlling the cross-linking agent and cross-linking degree. The effects of different cross-linking point structures on the structure and properties of aliphatic polyurethane were revealed. The optimal bonding strength and tensile strength can reach 1.7 MPa and 43 MPa, which are 170 % and 301 % higher than those of polyurethane, respectively. The transmittance of the aliphatic polyurethane can reach 80 %. Extremely superior impact resistance of the laminated safety glass based on the aliphatic polyurethane have been verified. The ultimate bearing capacity was 14 times of unmodified polyurethane. It will have huge application potential in the fields of aerospace, construction and automotive.</div></div>\",\"PeriodicalId\":405,\"journal\":{\"name\":\"Polymer\",\"volume\":\"318 \",\"pages\":\"Article 128002\"},\"PeriodicalIF\":4.1000,\"publicationDate\":\"2025-01-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0032386124013387\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0032386124013387","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Preparation and application of high strength, high transparency, and high impact resistance polyurethane elastomers by controlled cross-linking
In recent years, polyurethane elastomer has been widespread used in automotive, aerospace, and other fields depending on its wide range of adjustable properties, both high elasticity of rubber and plastic rigidity. Its high transparency and high strength have attracted increasing attention, especially in the application of laminated safety glass. In this work, an aliphatic polyurethane film with superior dynamic impact resistance, optical and mechanical properties were successfully obtained by controlling the cross-linking agent and cross-linking degree. The effects of different cross-linking point structures on the structure and properties of aliphatic polyurethane were revealed. The optimal bonding strength and tensile strength can reach 1.7 MPa and 43 MPa, which are 170 % and 301 % higher than those of polyurethane, respectively. The transmittance of the aliphatic polyurethane can reach 80 %. Extremely superior impact resistance of the laminated safety glass based on the aliphatic polyurethane have been verified. The ultimate bearing capacity was 14 times of unmodified polyurethane. It will have huge application potential in the fields of aerospace, construction and automotive.
期刊介绍:
Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics.
The main scope is covered but not limited to the following core areas:
Polymer Materials
Nanocomposites and hybrid nanomaterials
Polymer blends, films, fibres, networks and porous materials
Physical Characterization
Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films
Polymer Engineering
Advanced multiscale processing methods
Polymer Synthesis, Modification and Self-assembly
Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization
Technological Applications
Polymers for energy generation and storage
Polymer membranes for separation technology
Polymers for opto- and microelectronics.