含铕多改性剂硼磷硅锂铝玻璃的制备、结构特点及防辐射潜力

IF 2.8 3区 物理与天体物理 Q3 CHEMISTRY, PHYSICAL Radiation Physics and Chemistry Pub Date : 2024-12-31 DOI:10.1016/j.radphyschem.2024.112505
M.N. Vishnu Narayanan Namboothiri, K.A. Naseer, K. Marimuthu, M.I. Sayyed, A.F. Abd El-Rehim
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引用次数: 0

摘要

采用传统的熔融淬火技术合成了Eu3+离子混合硼磷铝锂玻璃基,用于辐射防护。通过XRD和FTIR表征谱,证实了玻璃的非晶态性质,并分析了由于官能团出现在玻璃中的几何构型。计算并报告了其物理性质。更大的刚性标题玻璃暴露了结构属性。力学性能结果表明,铕掺杂的多改性剂硼磷硅锂铝玻璃具有致密性。采用Tauc图法对标题玻璃的光学带隙进行了研究,并对直接跃迁和间接跃迁的带隙值进行了计算、讨论和报道。测定了玻璃的辐射屏蔽能力。在中能量范围内,玻璃的MAC值都非常接近,在0.077 ~ 0.078 cm2/g之间,在0.001 cm2/g以内。在0.511起始能量处,所测玻璃的hvl顺序如下:PBSASr祝辞PBSABa祝辞PBSAZn祝辞PBSACd。
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Fabrication, structural features and radiation prevention potential of Europium incorporated multi-modifier Li–Al borophospho-silicate glasses
A brand new series of Eu3+ ions blended Li–Al borophospho-silictae glass matrix were synthesized by conventional melt quenching technique for radiation protection applications. XRD and FTIR characteristic profiles were recorded to confirm the amorphous nature and to analyze the geometrical configuration due to the functional groups occurrence in the prepared glasses. Physical properties were calculated and reported. Greater rigidity of the titled glasses was exposed by the structural attributes. The results obtained from the mechanical properties reveal the compactness of the Europium incorporated multi-modifier Li–Al borophospho-silicate glasses. The optical band gap studies for the titled glasses were carried out by employing Tauc's plot method, and the band gap values for direct and indirect transitions were calculated, discussed and reported. The radiation shielding ability of the glasses has been determined. In the middle energy range, the MAC values of the glasses are all very close together, within 0.001 cm2/g between 0.077 and 0.078 cm2/g. The HVLs of the tested glasses at energies starting at 0.511 are in the following order: PBSACa > PBSASr > PBSABa > PBSAZn > PBSACd.
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来源期刊
Radiation Physics and Chemistry
Radiation Physics and Chemistry 化学-核科学技术
CiteScore
5.60
自引率
17.20%
发文量
574
审稿时长
12 weeks
期刊介绍: Radiation Physics and Chemistry is a multidisciplinary journal that provides a medium for publication of substantial and original papers, reviews, and short communications which focus on research and developments involving ionizing radiation in radiation physics, radiation chemistry and radiation processing. The journal aims to publish papers with significance to an international audience, containing substantial novelty and scientific impact. The Editors reserve the rights to reject, with or without external review, papers that do not meet these criteria. This could include papers that are very similar to previous publications, only with changed target substrates, employed materials, analyzed sites and experimental methods, report results without presenting new insights and/or hypothesis testing, or do not focus on the radiation effects.
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