微波烧结纳米碳化硅增强8SiC/Ti-3Cu复合材料:制备、耐磨性、抗菌功能和生物相容性。

IF 10 2区 医学 Q1 ENGINEERING, BIOMEDICAL Advanced Healthcare Materials Pub Date : 2025-01-05 DOI:10.1002/adhm.202403626
Xin Li, Ying-Chao Zhao, Dengfeng Yin, Ying Cai, Desheng Xiao, Ming-Chun Zhao, Cuie Wen, Andrej Atrens
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引用次数: 0

摘要

钛合金在生物医学应用中的重要意义是其作为植入式材料的广泛应用,如内部支撑和骨替代物。钛合金对微动磨损非常敏感,这导致了Ti植入物的早期失效。提高这种种植体的耐磨性对于延长种植体的使用寿命至关重要。基于结构-功能一体化的理念,本研究以纯Ti、Cu和纳米sic粉末为原料,采用微波烧结的方法,史无前例地设计并制备了具有良好耐磨性的抗菌8SiC/Ti- 3cu复合材料。为了比较,在相同的条件下,用微波烧结法制备了无sic的Ti-3Cu复合材料。在Ti-3Cu中添加8vol .%的SiC可显著降低复合材料的孔隙率和孔径。8SiC/Ti-3Cu合金的维氏硬度为353 HV,抗压强度为803 MPa,弹性模量为28.7 GPa,耐磨性显著提高(磨损率比Ti-3Cu降低70%)。此外,8SiC/Ti-3Cu具有优异的电化学耐腐蚀性,与MC3T3-E1细胞的生物相容性,对大肠杆菌的抑菌率超过99%。在8SiC/Ti-3Cu复合材料中结合了耐磨的纳米增强SiC和抗菌的Ti2Cu,使其成为一种非常有前途的植入材料。
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Microwave-Sintered Nano-SiC Reinforced 8SiC/Ti-3Cu Composite: Fabrication, Wear Resistance, Antibacterial Function, and Biocompatibility.

The significance of biomedical applications of Ti alloys is best emphasized by their widespread utilization as implantable materials, such as internal supports and bone replacements. Ti alloys are sensitive to fretting wear, which leads to the early failure of Ti implants. Improved wear resistance of such implants is essential to ensure a prolonged implant life. Based on the structure-function-integrated concept, this work unprecedentedly designs and fabricates an antibacterial 8SiC/Ti-3Cu composite with improved wear resistance using microwave sintering from pure Ti, Cu, and nano-SiC powders. For comparison, SiC-free Ti-3Cu composite is manufactured under the same conditions using microwave sintering. The addition of 8 vol.% SiC to Ti-3Cu significantly reduces the porosity and pore size of composites. The 8SiC/Ti-3Cu shows a Vickers hardness of 353 HV, compressive strength of 803 MPa, elastic modulus of 28.7 GPa, and a significantly increased wear resistance (wear rate decreased by 70% compared to Ti-3Cu). In addition, 8SiC/Ti-3Cu exhibits excellent electrochemical corrosion resistance, biocompatibility in relation to MC3T3-E1 cells, and a bacteriostatic rate over 99% against E. coli. The combination of the wear-resistant nano-reinforced SiC and antibacterial Ti2Cu in the 8SiC/Ti-3Cu composite renders it a highly promising implant material.

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来源期刊
Advanced Healthcare Materials
Advanced Healthcare Materials 工程技术-生物材料
CiteScore
14.40
自引率
3.00%
发文量
600
审稿时长
1.8 months
期刊介绍: Advanced Healthcare Materials, a distinguished member of the esteemed Advanced portfolio, has been dedicated to disseminating cutting-edge research on materials, devices, and technologies for enhancing human well-being for over ten years. As a comprehensive journal, it encompasses a wide range of disciplines such as biomaterials, biointerfaces, nanomedicine and nanotechnology, tissue engineering, and regenerative medicine.
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