{"title":"瓶装三态亚胺","authors":"Dominik Munz","doi":"10.1038/s41557-024-01700-z","DOIUrl":null,"url":null,"abstract":"Nitrenes are compounds featuring a monovalent nitrogen atom, and they are typically formed as transient intermediates in organic synthesis. They have been the subject of matrix studies for decades, but their stabilization remains challenging. Now, two independent works report the isolation of triplet arylnitrenes stabilized by a sterically encumbered substituent.","PeriodicalId":18909,"journal":{"name":"Nature chemistry","volume":"17 1","pages":"6-7"},"PeriodicalIF":19.2000,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Bottleable triplet nitrenes\",\"authors\":\"Dominik Munz\",\"doi\":\"10.1038/s41557-024-01700-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Nitrenes are compounds featuring a monovalent nitrogen atom, and they are typically formed as transient intermediates in organic synthesis. They have been the subject of matrix studies for decades, but their stabilization remains challenging. Now, two independent works report the isolation of triplet arylnitrenes stabilized by a sterically encumbered substituent.\",\"PeriodicalId\":18909,\"journal\":{\"name\":\"Nature chemistry\",\"volume\":\"17 1\",\"pages\":\"6-7\"},\"PeriodicalIF\":19.2000,\"publicationDate\":\"2025-01-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nature chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.nature.com/articles/s41557-024-01700-z\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nature chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.nature.com/articles/s41557-024-01700-z","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Nitrenes are compounds featuring a monovalent nitrogen atom, and they are typically formed as transient intermediates in organic synthesis. They have been the subject of matrix studies for decades, but their stabilization remains challenging. Now, two independent works report the isolation of triplet arylnitrenes stabilized by a sterically encumbered substituent.
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Nature Chemistry is a monthly journal that publishes groundbreaking and significant research in all areas of chemistry. It covers traditional subjects such as analytical, inorganic, organic, and physical chemistry, as well as a wide range of other topics including catalysis, computational and theoretical chemistry, and environmental chemistry.
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