烷基溴与胺羧基硼烷的合成反应

Organic chemistry frontiers : an international journal of organic chemistry Pub Date : 2025-01-22 DOI:10.1039/d4qo02325k

Changhee Park , Seyun Gi , Seongkyeong Yoon , Seong Jung Kwon , Sunggi Lee

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引用次数: 0

摘要

胺羧基硼烷使10、20和30烷基溴之间的卤素原子转移（XAT）有效，从而产生具有各种缺电子双键的吉斯加成产物。此外，用几个连接的羧基硼烷也可以直接加成几个硼基自由基。

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The Giese reaction of alkyl bromides using amine carboxyboranes†

Amine carboxyborane enabled efficient halogen atom transfer (XAT) with 1°, 2°, and 3° alkyl bromides, resulting in Giese addition products with various electron-deficient double bonds. Moreover, direct addition of several boryl radicals was also possible using several ligated carboxyboranes.

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来源期刊

Organic chemistry frontiers : an international journal of organic chemistry

CiteScore

7.80

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0.00%

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