利用印尼空棕榈果束:通过温度依赖热解合成生物炭。

IF 4.4 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY Nanomaterials Pub Date : 2024-12-31 DOI:10.3390/nano15010050
Fairuz Gianirfan Nugroho, Abu Saad Ansari, Nurul Taufiqu Rochman, Shubhangi Satish Khadtare, Vijaya Gopalan Sree, Nabeen K Shrestha, Afina Faza Hafiyyan, Hyunsik Im, Abu Talha Aqueel Ahmed
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引用次数: 0

摘要

生物质虽然是一种主要能源,但仍未得到充分利用。生物质热解生成的生物炭具有高孔隙率和高表面积,在光催化中具有增强催化活性和减少电子复合的催化剂载体作用。印度尼西亚是世界上最大的棕榈油生产国,在2023年生产了约1200万吨空果束(EFBs),使EFBs成为一种有前途的生物炭来源。本研究利用剩余的EFB纤维在500、800和1000°C下合成生物炭,通过红外和拉曼光谱分析结构变化,以及粒度和表面积分析,为未来的生物炭研究奠定基础。获得的最小粒径为71.1 nm,最大比表面积为10.6 × 102 m2/g。光谱分析表明,在1000°C下生产的生物炭产生的纳米石墨晶体尺寸约为5.47 nm。这提供了更高的缺陷密度,尽管电导率较低。其他研究表明,我们的生物炭可以用作各种绿色能源相关应用的催化剂载体,即反电极、电催化剂和光催化剂。
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Utilizing Indonesian Empty Palm Fruit Bunches: Biochar Synthesis via Temperatures Dependent Pyrolysis.

Biomass, though a major energy source, remains underutilized. Biochar from biomass pyrolysis, with its high porosity and surface area, is especially useful as catalyst support, enhancing catalytic activity and reducing electron recombination in photocatalysis. Indonesia, the world's top palm oil producer, generated around 12 million tons of empty fruit bunches (EFBs) in 2023, making EFBs a promising biochar source. This study synthesizes biochar from leftover EFB fibers at 500, 800, and 1000 °C, analyzing structural changes via infrared and Raman spectroscopy, along with particle size and surface area analysis, laying the groundwork for future biochar research. The smallest particle size and highest surface area gained was 71.1 nm and 10.6 × 102 m2/g. Spectroscopic analysis indicates that biochar produced at 1000 °C has produced nano-crystalline graphite with a crystallite size of approximately 5.47 nm. This provides higher defect density, although with lower conductivity. Other studies indicate that our biochar can be used as catalyst support for various green energy-related applications, i.e., counter electrodes, electrocatalysts, and photocatalysts.

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来源期刊
Nanomaterials
Nanomaterials NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
8.50
自引率
9.40%
发文量
3841
审稿时长
14.22 days
期刊介绍: Nanomaterials (ISSN 2076-4991) is an international and interdisciplinary scholarly open access journal. It publishes reviews, regular research papers, communications, and short notes that are relevant to any field of study that involves nanomaterials, with respect to their science and application. Thus, theoretical and experimental articles will be accepted, along with articles that deal with the synthesis and use of nanomaterials. Articles that synthesize information from multiple fields, and which place discoveries within a broader context, will be preferred. There is no restriction on the length of the papers. Our aim is to encourage scientists to publish their experimental and theoretical research in as much detail as possible. Full experimental or methodical details, or both, must be provided for research articles. Computed data or files regarding the full details of the experimental procedure, if unable to be published in a normal way, can be deposited as supplementary material. Nanomaterials is dedicated to a high scientific standard. All manuscripts undergo a rigorous reviewing process and decisions are based on the recommendations of independent reviewers.
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