层次核壳结构NiO@Cu2O-CF有效的非酶电化学葡萄糖检测。

IF 4.4 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY Nanomaterials Pub Date : 2024-12-30 DOI:10.3390/nano15010047
Yueyun Huang, Jiahua You, Yingru Ding, Yun Xie, Ting Wang, Fanglong Zhu, Weiping Gong, Zhenting Zhao
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引用次数: 0

摘要

非酶促血糖检测是控制糖尿病患者血糖水平的有效手段。制备了一种新型的基于泡沫铜(Ni(OH)2@Cu(OH)2-CF)的氢氧化镍壳包覆氢氧化铜芯的分层核壳结构,并从NiO@Cu2O-CF衍生出用于葡萄糖传感。循环伏安法和安培法实验证明了在碱性条件下葡萄糖的有效电化学催化作用。测量结果表明,该传感器的检测尺度为0.005 ~ 4.5 mM,检测灵敏度为4.67µa /µM/cm2。对750 μM葡萄糖(1.0 s/3.5 s)具有显著的响应/恢复时间,同时,NiO@Cu2O-CF对葡萄糖的测定具有显著的选择性、可靠的重复性和长期的稳定性,具有较好的应用前景。
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A Hierarchical Core-Shell Structure of NiO@Cu2O-CF for Effective Non-Enzymatic Electrochemical Glucose Detection.

Non-enzymatic glucose detection is an effective strategy to control the blood glucose level of diabetic patients. A novel hierarchical core-shell structure of nickel hydroxide shell coated copper hydroxide core based on copper foam (Ni(OH)2@Cu(OH)2-CF) was fabricated and derived from NiO@Cu2O-CF for glucose sensing. Cyclic voltammetry and amperometry experiments have demonstrated the efficient electrochemical catalysis of glucose under alkaline conditions. The measurement displays that the fabricated sensor exhibits a detection scale of 0.005-4.5 mM with a detection sensitivity of 4.67 µA/µM/cm2. It has remarkable response/recovery times in respect of 750 μM glucose (1.0 s/3.5 s). Moreover, the NiO@Cu2O-CF shows significant selectivity, reliable reproducibility and long-term stability for glucose determination, suggesting it is a suitable candidate for further applications.

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来源期刊
Nanomaterials
Nanomaterials NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
8.50
自引率
9.40%
发文量
3841
审稿时长
14.22 days
期刊介绍: Nanomaterials (ISSN 2076-4991) is an international and interdisciplinary scholarly open access journal. It publishes reviews, regular research papers, communications, and short notes that are relevant to any field of study that involves nanomaterials, with respect to their science and application. Thus, theoretical and experimental articles will be accepted, along with articles that deal with the synthesis and use of nanomaterials. Articles that synthesize information from multiple fields, and which place discoveries within a broader context, will be preferred. There is no restriction on the length of the papers. Our aim is to encourage scientists to publish their experimental and theoretical research in as much detail as possible. Full experimental or methodical details, or both, must be provided for research articles. Computed data or files regarding the full details of the experimental procedure, if unable to be published in a normal way, can be deposited as supplementary material. Nanomaterials is dedicated to a high scientific standard. All manuscripts undergo a rigorous reviewing process and decisions are based on the recommendations of independent reviewers.
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