New Insights on Iron-Trimesate MOFs for Inorganic As(III) and As(V) Adsorption from Aqueous Media.

Arsenic contamination of water endangers the health of millions of people worldwide, affecting certain countries and regions with especial severity. Interest in the use of Fe-based metal organic frameworks (MOFs) to remove inorganic arsenic species has increased due to their stability and adsorptive properties. In this study, the performance of a synthesized Nano-{Fe-BTC} MOF, containing iron oxide octahedral chains connected by trimesic acid linkers, in adsorbing As(III) and As(V) species was investigated and compared with commercial Basolite^®F300 MOF. Despite their similarities in composition, they exhibit distinct structural characteristics in their porosity, pore size, and surface areas, which affected the adsorption processes. The kinetic data of the adsorption of As(III) and As(V) by both Fe-MOFs fitted the pseudo second-order model well, with the kinetic constant being higher for Basolite^®F300 given its higher porosity. Intraparticle diffusion was, in both cases, the rate controlling step with the contribution of film diffusion in the adsorption processes, which achieved equilibrium after 1 h. The maximum adsorption capacity for As(V), 41.66 mg g^-1, was obtained with Basolite^®F300 at the 6.5-10 pH range, whereas Nano-{Fe-BTC} showed a different behaviour as maximum adsorption (14.99 mg g^-1) was obtained at pH 2. However, both adsorbents exhibited the same performance for As(III) adsorption, which is not adsorbed at pH < 9. The Langmuir adsorption isotherm model fitted well for As(III) and As(V) adsorption by Nano-{Fe-BTC} and As(III) by Basolite^®F300, whereas the Freundlich model fitted best for As(V) given its superior structural properties.