过程和产品模型中反应速率的估计

IF 0.4 Q4 ENGINEERING, MECHANICAL Journal of Machinery Manufacture and Reliability Pub Date : 2025-01-12 DOI:10.1134/S1052618824701462

A. V. Ragutkin, M. E. Stavrovskii, I. N. Kravchenko, I. M. Sidorov, E. S. Postnikova

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引用次数: 0

摘要

从化学动力学的角度考虑了反应速率对温度和压力的依赖关系，并试图解释了当接触面上的载荷减小并随着滑动速度的增加而达到最小时摩擦力的增加。热力学方面的过渡状态理论和情况下，其中的反应本身导致偏离平衡考虑。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Estimation of the Reaction Rate in Models of Processes and Products

The dependence of the reaction rate on temperature and pressure is considered from the standpoint of chemical kinetics, and an attempt is made to explain the increase in friction force after a decreasing load on the contacting surfaces and attaining the minimum with an increase in the sliding velocity. Thermodynamic aspects of the transition state theory and the cases wherein the reaction itself causes resulting deviations from equilibrium are considered.

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来源期刊

Journal of Machinery Manufacture and Reliability ENGINEERING, MECHANICAL-

CiteScore

0.80

自引率

33.30%

发文量

期刊介绍： Journal of Machinery Manufacture and Reliability is devoted to advances in machine design; CAD/CAM; experimental mechanics of machines, machine life expectancy, and reliability studies; machine dynamics and kinematics; vibration, acoustics, and stress/strain; wear resistance engineering; real-time machine operation diagnostics; robotic systems; new materials and manufacturing processes, and other topics.