“平行+单轴”共轭静电纺丝制备具有多色发射和磁性的双功能类似三色微纤维薄膜

IF 17.3 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Matter Pub Date : 2025-01-14 DOI:10.1016/j.matt.2024.101946
Xintong Huo, Yunrui Xie, Yuqi Sheng, Yaolin Hu, Haina Qi, Hong Shao, Qianli Ma, Wensheng Yu, Guixia Liu, Xiangting Dong
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引用次数: 0

摘要

提出了创新的“平行+单轴”共轭静电纺丝技术,并利用该技术合成了一种独特的具有多色发射和磁性可调的{[CsPbBr3/聚苯乙烯(PS)]//[CoFe2O4/PS]}||[CsPb(Br0.06/I0.94)3/PS]模拟三色超纤薄膜(ATMF)。这种类似的三色微纤维作为结构元件实现了三个独立的微观分区,将具有绿色荧光的CsPbBr3钙钛矿量子点(QDs)、具有红色荧光的CsPb(Br0.06/I0.94)3量子点和磁性CoFe2O4组装在各自的分区中。因此,避免了深色CoFe2O4对两种钙钛矿量子点荧光的不利影响,并且两种钙钛矿量子点的微观空间分离充分解决了它们之间不正常的卤素阴离子交换,从而获得超荧光-磁分岔。使用蓝色芯片和ATMF作为荧光粉封装的发光二极管(led)显示白光荧光。提出了类似三色超细纤维和ATMF的形成机理,并建立了相应的简易构建技术,避免了复杂的工艺过程。这项工作为其他多功能材料的设计和制备提供了支持。
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“Parallel+uniaxial” conjugated electrospinning for dual-function analogous-tricolor microfiber film with multicolor emission and magnetism
Innovative “parallel+uniaxial” conjugated electrospinning is advanced and utilized to synthesize a unique {[CsPbBr3/polystyrene (PS)]//[CoFe2O4/PS]}||[CsPb(Br0.06/I0.94)3/PS] analogous-tricolor microfiber film (ATMF) with multicolor emission and tunable magnetism. This analogous-tricolor microfiber as a structural element accomplishes three independent microcosmic partitions to assemble CsPbBr3 perovskite quantum dots (QDs) with green fluorescence, CsPb(Br0.06/I0.94)3 QDs with red fluorescence, and magnetic CoFe2O4 into their respective partitions. As a result, the adverse impacts of dark-colored CoFe2O4 on the fluorescence of the two perovskite QDs are shunned, and the microcosmic spatial separation of the two kinds of perovskite QDs fully addresses infaust halogen anion exchange between them to receive super fluorescence-magnetic bifuction. The light-emitting diodes (LEDs) packaged using blue chips and ATMF as phosphor exhibit white-light fluorescence. The formation mechanisms of the analogous-tricolor microfiber and ATMF are advanced, and corresponding facile construction techniques are established to shun complex processes. This work provides support for the design and preparation of other multifunctional materials.
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来源期刊
Matter
Matter MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
26.30
自引率
2.60%
发文量
367
期刊介绍: Matter, a monthly journal affiliated with Cell, spans the broad field of materials science from nano to macro levels,covering fundamentals to applications. Embracing groundbreaking technologies,it includes full-length research articles,reviews, perspectives,previews, opinions, personnel stories, and general editorial content. Matter aims to be the primary resource for researchers in academia and industry, inspiring the next generation of materials scientists.
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