氧化锌锡(ZTO)的氧依赖性光致发光和电导率:一种改进的Stern-Volmer描述。

IF 2.3 3区 化学 Q3 CHEMISTRY, PHYSICAL Chemphyschem Pub Date : 2025-01-14 DOI:10.1002/cphc.202400984
Linda Kothe, Josefin Klippstein, Marvin Kloß, Marc Wengenroth, Michael Poeplau, Stephan Ester, Michael Tiemann
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引用次数: 0

摘要

研究了氧化锌锡(ZTO)作为氧(O2)光致发光传感器的性能。化学吸收的氧使发光强度猝灭。同时,ZTO也作为电阻式传感器进行了研究;作为一种n型半导体,其电导率因氧的吸附而降低。这两种现象都可以用于定量的氧传感。各自的传感器响应可以用相同的改进的Stern-Volmer模型来描述,该模型分别区分可接近和不可接近的发光中心或载流子。温度的影响研究范围从室温到150°C。
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Oxygen-Dependent Photoluminescence and Electrical Conductance of Zinc Tin Oxide (ZTO): A Modified Stern-Volmer Description.

Zinc tin oxide (ZTO) is investigated as a photoluminescent sensor for oxygen (O2); chemisorbed oxygen quenches the luminescence intensity. At the same time, ZTO is also studied as a resistive sensor; being an n-type semiconductor, its electrical conductance decreases by adsorption of oxygen. Both phenomena can be exploited for quantitative O2 sensing. The respective sensor responses can be described by the same modified Stern-Volmer model that distinguishes between accessible and non-accessible luminescence centers or charge carriers, respectively. The impact of the temperature is studied in the range from room temperature up to 150 °C.

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来源期刊
Chemphyschem
Chemphyschem 化学-物理:原子、分子和化学物理
CiteScore
4.60
自引率
3.40%
发文量
425
审稿时长
1.1 months
期刊介绍: ChemPhysChem is one of the leading chemistry/physics interdisciplinary journals (ISI Impact Factor 2018: 3.077) for physical chemistry and chemical physics. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. ChemPhysChem is an international source for important primary and critical secondary information across the whole field of physical chemistry and chemical physics. It integrates this wide and flourishing field ranging from Solid State and Soft-Matter Research, Electro- and Photochemistry, Femtochemistry and Nanotechnology, Complex Systems, Single-Molecule Research, Clusters and Colloids, Catalysis and Surface Science, Biophysics and Physical Biochemistry, Atmospheric and Environmental Chemistry, and many more topics. ChemPhysChem is peer-reviewed.
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