Trends in Heavy Metal Pollution in Agricultural Land Soils of Tropical Islands in China (2000-2024): A Case Study on Hainan Island.

Heavy metal contamination in agricultural soils has garnered increasing attention, yet research on the spatiotemporal trends of heavy metal pollution in tropical regions with multiple annual crop harvests remains limited. This study examines data from 41 studies published between 2000 and 2024, including 206 records from 4122 sampling points on Hainan Island in China, to investigate the spatial distribution and temporal trends of heavy metal pollution. The results reveal that the average concentrations of Cd, Pb, As, Cr, and Hg in surface soil samples from agricultural lands on Hainan Island are 0.12, 28.28, 4.36, 63.98, and 0.075 mg/kg, respectively, all below the risk screening thresholds set by the Soil Pollution Risk Control Standard for Agricultural Land (GB 15618-2018). Spatially, heavy metal concentrations exhibit considerable regional variation. Cd levels are lower in the central region but higher in the northern and southern parts of the island. Both the cumulative pollution index and potential ecological risk index are elevated at the northern and southern ends, indicating more severe pollution in these areas. Pb and As show similar spatial patterns, with higher concentrations in the west and lower concentrations in the east. Conversely, Cr has higher concentrations in the northeast and lower concentrations in the southwest. Hg levels are elevated at the northern and southern ends of the island, though the overall pollution and ecological risk in these areas remain relatively low. Temporally, the concentration of heavy metals in agricultural soils has increased overall over the past two decades, with peak values occurring between 2017 and 2023. From 2002 to 2013, the variation was modest, while the largest fluctuations occurred between 2014 and 2016. Among the metals, Cr exhibited the most significant increase, indicating the most severe pollution, followed by Cd and Hg. As and Pb showed relatively lower levels of contamination. Regarding exceedance rates, the exceedances were evaluated against the thresholds established in GB15618-2018 and GB15618-1995. Cd's exceedance rate increased from approximately 1% between 2002 and 2014 to between 7.78% and 20.93% in the following years, peaking in 2017. The exceedance rate for As rose slightly from 0% to 0.83%, with sporadic exceedances starting in 2015. Although these were relatively minor, a severe pollution point for As was observed in 2019. Exceedance rates for Pb and Cr increased significantly, from 0.75% and 7.50% in 2019 to 1.94% and 9.44% in 2023, reflecting increases of 4.8 to 10 times. These findings underscore the need for strengthened monitoring and management of heavy metal pollution in agricultural soils on Hainan Island to safeguard land quality and ensure the sustainability of local agricultural practices.