{"title":"一种具有可变反应性的镓化合物","authors":"","doi":"10.1038/s44160-024-00653-y","DOIUrl":null,"url":null,"abstract":"Singly bonded, low-valent group 13 compounds are rare, and their reactions are typically limited to oxidative additions. Now, a compound with a singly bonded gallium(i) centre has been prepared using a sterically hindered ligand. This compound exhibits varied reactivity, undergoing both oxidative addition and redox-invariant carbometallation reactions.","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"4 1","pages":"11-12"},"PeriodicalIF":0.0000,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A gallium(i) compound with variable reactivity\",\"authors\":\"\",\"doi\":\"10.1038/s44160-024-00653-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Singly bonded, low-valent group 13 compounds are rare, and their reactions are typically limited to oxidative additions. Now, a compound with a singly bonded gallium(i) centre has been prepared using a sterically hindered ligand. This compound exhibits varied reactivity, undergoing both oxidative addition and redox-invariant carbometallation reactions.\",\"PeriodicalId\":74251,\"journal\":{\"name\":\"Nature synthesis\",\"volume\":\"4 1\",\"pages\":\"11-12\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-09-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nature synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.nature.com/articles/s44160-024-00653-y\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"0\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nature synthesis","FirstCategoryId":"1085","ListUrlMain":"https://www.nature.com/articles/s44160-024-00653-y","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"0","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Singly bonded, low-valent group 13 compounds are rare, and their reactions are typically limited to oxidative additions. Now, a compound with a singly bonded gallium(i) centre has been prepared using a sterically hindered ligand. This compound exhibits varied reactivity, undergoing both oxidative addition and redox-invariant carbometallation reactions.
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