从废弃水生植物中探索生物质衍生的微晶纤维素:聚合物复合材料增强物的综合表征。

IF 8.7 1区 化学 Q1 BIOCHEMISTRY & MOLECULAR BIOLOGY International Journal of Biological Macromolecules Pub Date : 2025-04-01 Epub Date: 2025-01-21 DOI:10.1016/j.ijbiomac.2025.140217
Ajith J Kings, Indran Suyambulingam, Sunesh Narayanaperumal, L R Monisha Miriam, Divya Divakaran, Adhigan Murali, Sung Soo Han
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引用次数: 0

摘要

创造具有更好性能的聚合物复合材料是一件至关重要的事情。纤维素填充材料在高分子复合材料中越来越受欢迎。本研究以水生植物大薸叶片为原料提取纤维素。采用弱浓度化学试剂酸水解法提取纤维素。主要目的是评估纤维素的特性及其作为复合材料增强剂的潜力。纤维素微填料的表面、热学和理化性质是主要的研究领域。为了确定纤维素的组成,进行了广泛的化学表征分析。x射线衍射研究表明,层状豆叶纤维素结晶度指数为75.9 %,晶粒尺寸为8.2 nm。用傅里叶变换红外光谱仪检测纤维素的官能团。扫描电镜图像显示表面光滑,颗粒形状扭曲。通过ImageJ软件计算得到的平均粒径为23.253 ± 6.55 μm。提取的微纤维素的平均粗糙度值为28.296 μm,可接受。研究表明,在构建复合材料时,层状Pistia叶片纤维素(PSC)的表面特性有利于与其他基质形成界面键。BET的表面积也明显更高。该材料仅在215 °C高温下降解,通过TG分析进行了分析。研究结果表明,一种植物Pistia stratiotes的性能优于棉花、大麻和木材等更传统的微纤维素来源。作为合成增强材料的绿色替代品,回收的微纤维素在许多行业都有潜在的用途。
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Exploring biomass derived microcrystalline cellulose from the waste aquatic plant Pistia stratiotes: A comprehensive characterization for polymer composite reinforcement.

The creation of polymer composites with better performance is a crucial thing. The cellulosic filler material gain popularity in polymer composites. In this study, aquatic plant Pistia stratiote leaves were used as a raw material for cellulose extraction. The cellulose was extracted via acid hydrolysis method with mild concentration chemicals. The main aim was to assess the cellulose characteristics and its potential as a reinforcement for composites. Surface, thermal, and physicochemical properties of the micro fillers made of cellulose were the primary areas of research. To determine the composition of the cellulose, extensive chemical characterization analyses were conducted. According to X-ray diffraction studies, Pistia stratiotes leaves cellulose have a crystallinity index of 75.9 % and crystalline size of 8.2 nm. Cellulosic functional groups were revealed by examination using a Fourier Transform Infrared Spectrometer. Scanning electron microscopy images revealed smooth surface and distorted shaped particles. The average particle size, which was calculated using the ImageJ software, was 23.253 ± 6.55 μm. The extracted micro cellulose had an acceptable average roughness value of 28.296 μm, as shown by atomic force microscopy images. Surface properties of the Pistia stratiotes leaves cellulose (PSC) were shown to be conducive to the formation of interfacial bonds with other matrices while composites are being built. The BET surface areas are significantly higher as well. The material degrades only at high temperatures 215 °C, which was analysed by TG analysis. The findings demonstrate that Pistia stratiotes, a plant, outperforms more conventional sources of micro cellulose, such as cotton, hemp, and wood. As a greener alternative to synthetic reinforcements, the recovered micro cellulose has potential uses across numerous industries.

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来源期刊
International Journal of Biological Macromolecules
International Journal of Biological Macromolecules 生物-生化与分子生物学
CiteScore
13.70
自引率
9.80%
发文量
2728
审稿时长
64 days
期刊介绍: The International Journal of Biological Macromolecules is a well-established international journal dedicated to research on the chemical and biological aspects of natural macromolecules. Focusing on proteins, macromolecular carbohydrates, glycoproteins, proteoglycans, lignins, biological poly-acids, and nucleic acids, the journal presents the latest findings in molecular structure, properties, biological activities, interactions, modifications, and functional properties. Papers must offer new and novel insights, encompassing related model systems, structural conformational studies, theoretical developments, and analytical techniques. Each paper is required to primarily focus on at least one named biological macromolecule, reflected in the title, abstract, and text.
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