工业后皮革废弃物在可持续橡胶复合材料开发中的应用。

IF 5.8 3区 工程技术 Q1 POLYMER SCIENCE Polymers Pub Date : 2025-01-14 DOI:10.3390/polym17020190
G Barrera Torres, Carlos M Gutierrez Aguilar, Elizabeth R Lozada, Manuel J Tabares Montoya, Beatriz E Ángel Álvarez, Juan C Sánchez, Jaime A Jaramillo Carvalho, Renivaldo J Santos
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引用次数: 0

摘要

在皮革加工过程中产生的大量废物以及在制造的其他阶段是皮革工业中反复出现的问题,本文试图解决这个问题。为了研究所得复合材料的机械和热特性,本研究建议使用来自牛皮革工业的皮革废料,分析制革过程,并评估将该废料与天然橡胶(TSR-20)混合的可行性。在不含皮革废料的情况下,合成的复合材料具有优异的抗拉强度,超过了橡胶强度的100%。利用洛伦兹-帕克方程证明了再生皮革颗粒与天然橡胶基体的有效相互作用。这种更好的性能表明橡胶和皮革废料之间存在竞争关系。样品的密度比聚丁二烯弹性体高10%,比天然皮革高10%,而硬度与通用鞋底设计中经常使用的PVC相当。这表明,皮革工业的废物可以有效地用于可持续的应用,特别是在皮革制品和鞋子的生产中,有助于使通常被丢弃的废物增值。此外,通过鼓励在创造新化合物时使用回收资源,该计划为橡胶行业提供了一个可持续的选择。为了优化这一建议,可能有必要确定不同的硫化体系,以改善物理机械性能和其他从优化中获得的用途。这种复合材料可以应用于时尚行业,以发展新的趋势,围绕废物和残留物的应用为自然设计线。通过研究过程,可以将残留物整合到天然橡胶基体中,这一点在表征过程中得到了证明。
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Application of Post-Industrial Leather Waste for the Development of Sustainable Rubber Composites.

The substantial waste generated during the processing of hides and skins as well as at other stages of manufacturing is a recurring issue in the leather industry that this article attempts to address. To investigate the mechanical and thermal characteristics of the resultant composites, this study suggests using leather waste from the bovine leather industry, analyzes the tanning process, and assesses the viability of mixing this waste with natural rubber (TSR-20). Without the inclusion of leather waste, the resulting composites had exceptional tensile strength, surpassing 100% of rubber's strength. The effective interaction of the recycled leather particles with the natural rubber matrix was evidenced using the Lorentz-Park equation. This better performance points to a competitive relationship between rubber and leather waste. The samples' density was 10% greater than that of polybutadiene elastomers and 10% greater than that of natural leather, while the hardness was comparable to that of PVC, which is frequently utilized in the design of general-purpose soles. This suggests that waste from the leather industry can be efficiently utilized in sustainable applications, particularly in the production of leather goods and shoes, helping to valorize waste that is typically discarded. Furthermore, by encouraging the use of recycled resources in the creation of new compounds, this plan provides the rubber sector with a sustainable option. To optimize this proposal, perhaps will be necessary to identify different vulcanization systems to improve the physical mechanical properties and other uses derived from the optimizations realized. This composite can be applied in the fashion industry in order to develop new trends around the application of waste and residues for a natural design line. Through the research process, it was possible to integrate the residues into the natural rubber matrix, as evidenced in the characterization process.

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来源期刊
Polymers
Polymers POLYMER SCIENCE-
CiteScore
8.00
自引率
16.00%
发文量
4697
审稿时长
1.3 months
期刊介绍: Polymers (ISSN 2073-4360) is an international, open access journal of polymer science. It publishes research papers, short communications and review papers. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Polymers provides an interdisciplinary forum for publishing papers which advance the fields of (i) polymerization methods, (ii) theory, simulation, and modeling, (iii) understanding of new physical phenomena, (iv) advances in characterization techniques, and (v) harnessing of self-assembly and biological strategies for producing complex multifunctional structures.
期刊最新文献
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