预应力细胞超材料中温度驱动的拓扑变换

IF 19 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Advanced Functional Materials Pub Date : 2025-01-26 DOI:10.1002/adfm.202413962
Hang Yang, Wei-Jie Wang, Jun-Zhe Zhu, Li Ma, Damiano Pasini, Wei Zhai
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引用次数: 0

摘要

刺激响应材料能够在暴露于外部触发(例如热、光或湿度)时改变其物理化学性质,例如形状、颜色或硬度,表现出环境适应性。它们经历形状重构、模式转换和属性调制的能力使其具有多功能性。在这项工作中,利用两种策略,即预应力组装和温度相关的刚度反转,来引入一类能够进行拓扑变换的温度响应超材料,赋予它们智能功能。通过力学理论、数值模拟和热力学实验的结合,首先阐明了温度触发的拓扑转换导致模式切换的物理机制,然后利用这些见解来演示可调带隙和机器人捕获器。这些结果表明,在热驱动下,在相当快的时间范围内(小于6 s)实现了热膨胀系数的巨大负值和正值,并伴随着各向同性的膨胀和收缩。这里提出的策略是通用的,因为它依赖于一对现成的3D打印材料,可以向上和向下缩放,也可以通过其他物理刺激实现,例如光和水分,为多功能应用铺平了道路,包括刺激触发的变形设备,自主传感器和执行器,以及可重构的软机器人。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Temperature-Driven Topological Transformations in Prestressed Cellular Metamaterials

Stimuli-responsive materials are able to alter their physicochemical properties, e.g., shape, color, or stiffness, upon exposure to an external trigger, e.g., heat, light, or humidity, exhibiting environmental adaptability. Their capacity to undergo shape reconfiguration, pattern transformation, and property modulation enables multifunctionality. In this work, two strategies are harnessed, i.e., prestressed assembly and temperature-dependent stiffness reversal, to introduce a class of temperature-responsive metamaterials capable of undergoing topological transformations, endowing them with smart functionality. Through a combination of mechanics theory, numerical simulations, and thermomechanical experiments, the physical mechanisms underlying the temperature-triggered topological transformations leading to pattern switches are first elucidated, and then the insights are leveraged to demonstrate tunable bandgaps and robotic capturers. These findings reveal the attainment of giant negative and positive values of coefficient of thermal expansion, accompanied by isotropic expansion and shrinkage under thermal actuation within a fairly rapid timeframe, below 6 s. The strategy here presented is versatile as it relies on a pair of off-the-shelf 3D printable materials, can be up- and down-scaled, and can also be realized through other physical stimuli, e.g., light and moisture, paving the way for use in multifunctional applications, including stimulus-triggered morphing devices, autonomous sensors and actuators, and reconfigurable soft robots.

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来源期刊
Advanced Functional Materials
Advanced Functional Materials 工程技术-材料科学:综合
CiteScore
29.50
自引率
4.20%
发文量
2086
审稿时长
2.1 months
期刊介绍: Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week. Advanced Functional Materials is known for its rapid and fair peer review, quality content, and high impact, making it the first choice of the international materials science community.
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