锌（TFSI）2介导开环聚合制备稳定锌金属水电池的电解质工程

IF 36.3 1区材料科学 Q1 Engineering Nano-Micro Letters Pub Date : 2025-01-28 DOI:10.1007/s40820-025-01649-9

Zhenjie Liu, Murong Xi, Rui Sheng, Yudai Huang, Juan Ding, Zhouliang Tan, Jiapei Li, Wenjun Zhang, Yonggang Wang

{"title":"锌（TFSI）2介导开环聚合制备稳定锌金属水电池的电解质工程","authors":"Zhenjie Liu, Murong Xi, Rui Sheng, Yudai Huang, Juan Ding, Zhouliang Tan, Jiapei Li, Wenjun Zhang, Yonggang Wang","doi":"10.1007/s40820-025-01649-9","DOIUrl":null,"url":null,"abstract":"<div><h2>Highlights</h2><div>\n \n <ul>\n <li>\n <p>A novel electrolyte enabled by Zn(TFSI)<sub>2</sub>-mediated ring-opening polymerization strategy for highly reversible aqueous zinc metal batteries was proposed.</p>\n </li>\n <li>\n <p>The novel electrolyte has good antioxidant stability and non-inflammability.</p>\n </li>\n <li>\n <p>The novel electrolyte widens the electrochemical window, improves the low-temperature performance, and inhibits Zn dendrite. The Zn metal anode shows an 8200 h lifespan at 1 mAh cm<sup>−2</sup> and a 2500 h lifespan at 60% depth of discharge.</p>\n </li>\n </ul>\n </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"17 1","pages":""},"PeriodicalIF":36.3000,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-025-01649-9.pdf","citationCount":"0","resultStr":"{\"title\":\"Zn(TFSI)2-Mediated Ring-Opening Polymerization for Electrolyte Engineering Toward Stable Aqueous Zinc Metal Batteries\",\"authors\":\"Zhenjie Liu, Murong Xi, Rui Sheng, Yudai Huang, Juan Ding, Zhouliang Tan, Jiapei Li, Wenjun Zhang, Yonggang Wang\",\"doi\":\"10.1007/s40820-025-01649-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><h2>Highlights</h2><div>\\n \\n <ul>\\n <li>\\n <p>A novel electrolyte enabled by Zn(TFSI)<sub>2</sub>-mediated ring-opening polymerization strategy for highly reversible aqueous zinc metal batteries was proposed.</p>\\n </li>\\n <li>\\n <p>The novel electrolyte has good antioxidant stability and non-inflammability.</p>\\n </li>\\n <li>\\n <p>The novel electrolyte widens the electrochemical window, improves the low-temperature performance, and inhibits Zn dendrite. The Zn metal anode shows an 8200 h lifespan at 1 mAh cm<sup>−2</sup> and a 2500 h lifespan at 60% depth of discharge.</p>\\n </li>\\n </ul>\\n </div></div>\",\"PeriodicalId\":714,\"journal\":{\"name\":\"Nano-Micro Letters\",\"volume\":\"17 1\",\"pages\":\"\"},\"PeriodicalIF\":36.3000,\"publicationDate\":\"2025-01-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://link.springer.com/content/pdf/10.1007/s40820-025-01649-9.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nano-Micro Letters\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s40820-025-01649-9\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nano-Micro Letters","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s40820-025-01649-9","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Engineering","Score":null,"Total":0}

引用次数: 0

摘要

提出了一种基于Zn(TFSI)2介导开环聚合的高可逆锌金属水电池电解质。该新型电解质具有良好的抗氧化稳定性和不燃性。该新型电解质拓宽了电化学窗口，提高了低温性能，抑制了Zn枝晶的形成。锌金属阳极在1毫安时的寿命为8200小时，在放电深度为60%时的寿命为2500小时。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Zn(TFSI)2-Mediated Ring-Opening Polymerization for Electrolyte Engineering Toward Stable Aqueous Zinc Metal Batteries

Highlights

A novel electrolyte enabled by Zn(TFSI)₂-mediated ring-opening polymerization strategy for highly reversible aqueous zinc metal batteries was proposed.
The novel electrolyte has good antioxidant stability and non-inflammability.
The novel electrolyte widens the electrochemical window, improves the low-temperature performance, and inhibits Zn dendrite. The Zn metal anode shows an 8200 h lifespan at 1 mAh cm⁻² and a 2500 h lifespan at 60% depth of discharge.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Nano-Micro Letters NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY

CiteScore

32.60

自引率

4.90%

发文量

981

审稿时长

1.1 months

期刊介绍： Nano-Micro Letters is a peer-reviewed, international, interdisciplinary, and open-access journal published under the SpringerOpen brand. Nano-Micro Letters focuses on the science, experiments, engineering, technologies, and applications of nano- or microscale structures and systems in various fields such as physics, chemistry, biology, material science, and pharmacy.It also explores the expanding interfaces between these fields. Nano-Micro Letters particularly emphasizes the bottom-up approach in the length scale from nano to micro. This approach is crucial for achieving industrial applications in nanotechnology, as it involves the assembly, modification, and control of nanostructures on a microscale.