用粉煤灰合成ZSM-5型沸石:纯硅铝源。

IF 3.1 4区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY ChemistryOpen Pub Date : 2025-01-28 DOI:10.1002/open.202400314
Thapelo Manyepedza, Emmanuel V. Gaolefufa, Isaac N. Beas, Manoko Maubane-Nkadimeng, Moses T. Kabomo
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摘要

本研究探索了使用高纯度介孔二氧化硅合成ZSM-5分子筛,该分子筛完全来源于粉煤灰(CFA),无需额外的二氧化硅或氧化铝来源。传统的ZSM-5合成依赖于昂贵且对环境有害的纯化学品,而这种方法利用了工业副产品CFA,解决了成本和可持续性问题。经XRD、SEM、TEM、FTIR、TGA、BET等分析证实,合成的ZSM-5分子筛纯度高,比表面积为455.24 m2/g,具有独特的结构性质。该方法突出了cfa衍生二氧化硅作为沸石生产可持续原料的潜力,促进了环境可持续性和经济高效的工业应用在催化、吸附和分离过程中。
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ZSM-5 Zeolite Synthesis from Coal Fly Ash Synthesised Silica: Sole Silica & Alumina Source

This study explores the synthesis of ZSM-5 zeolite using high-purity mesoporous silica exclusively derived from coal fly ash (CFA), eliminating the need for additional silica or alumina sources. Traditional ZSM-5 synthesis relies on costly and environmentally harmful pure chemicals, whereas this approach utilizes CFA, an industrial byproduct, addressing both cost and sustainability concerns. The synthesized ZSM-5 zeolite demonstrates exceptional purity, with a surface area of 455.24 m2/g, and exhibits unique structural properties, confirmed through XRD, SEM, TEM, FTIR, TGA, and BET analyses. This method highlights the potential of CFA-derived silica as a sustainable feedstock for zeolite production, promoting both environmental sustainability and cost-effective industrial applications in catalysis, adsorption, and separation processes.

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来源期刊
ChemistryOpen
ChemistryOpen CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
4.80
自引率
4.30%
发文量
143
审稿时长
1 months
期刊介绍: ChemistryOpen is a multidisciplinary, gold-road open-access, international forum for the publication of outstanding Reviews, Full Papers, and Communications from all areas of chemistry and related fields. It is co-owned by 16 continental European Chemical Societies, who have banded together in the alliance called ChemPubSoc Europe for the purpose of publishing high-quality journals in the field of chemistry and its border disciplines. As some of the governments of the countries represented in ChemPubSoc Europe have strongly recommended that the research conducted with their funding is freely accessible for all readers (Open Access), ChemPubSoc Europe was concerned that no journal for which the ethical standards were monitored by a chemical society was available for such papers. ChemistryOpen fills this gap.
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