聚合物胶囊对碳酸盐砂一维压缩蠕变的影响

IF 4.6 2区 工程技术 Q2 ENGINEERING, CHEMICAL Powder Technology Pub Date : 2025-03-31 Epub Date: 2025-01-25 DOI:10.1016/j.powtec.2025.120705
Ke Chen , Ting Yao , Rui Qi , Sérgio D.N. Lourenço
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引用次数: 0

摘要

碳酸盐岩砂广泛分布于沿海地区,由于其高应力依赖性和时间依赖性(蠕变)压缩性而面临挑战。虽然土壤稳定技术传统上侧重于提高碳酸盐砂的强度,但对胶结碳酸盐砂的可压缩性性能的评估仍然是大多数设想的实际应用的关键方面。鉴于土壤自修复稳定方法的最新发展,本研究探讨了海藻酸钙/桐油胶囊在碳酸盐砂中降低压缩性的潜力。包封的桐油起到愈合剂的作用,经过30天的干燥,在砂粒的压实、硬化和粘接过程中,由于孔隙比的变化,桐油在砂粒内部逐渐释放。对不同初始相对密度和粒径的净砂和砂囊复合材料进行了长期逐步一维压缩试验。细砂-胶囊复合材料的整体压缩性和应力相关性降低,而胶囊对中、粗砂-胶囊复合材料的压缩性有不利影响。所有砂-胶囊复合材料的弹性响应均增加,而非减少蠕变。桐油胶结可以防止砂土在加载过程中颗粒破碎,从而降低砂土的可压缩性。通过热分析、CT扫描和显微分析进一步研究了不同粒径碳酸盐砂中胶囊的稳定机理,发现胶囊的可压缩性取决于胶囊中桐油的释放量,而桐油的释放量受砂-胶囊复合材料的孔隙结构控制。
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Effect of polymeric capsules on one-dimensional compression and creep of carbonate sand
Carbonate sand, widely distributed in coastal regions, presents challenge due to its high stress-dependent and time-dependent (creep) compressibility. While soil stabilization techniques have traditionally focused on enhancing the strength of carbonate sand, the evaluation on the compressibility performance of cemented carbonate sand remains a critical aspect for most envisaged practical applications. In light of recent developments in self-healing approaches for soil stabilization, this study investigated the potential of calcium alginate/Tung oil capsules to mitigate compressibility in carbonate sand. The encapsulated Tung oil serves as a healing agent, gradually releasing within the sand matrix when subjected to void ratio changes during compaction, hardening and bonding sand grains after a 30-day drying. Long-term stepwise one-dimensional compression tests were conducted on both clean sand and sand-capsule composite with different initial relative density and particle size. The overall and stress-dependent compressibility was reduced for fine sand-capsule composite, while capsules had adverse effect on the compressibility of medium and coarse sand-capsule composite. Capsules could not reduce the creep but increase the elastic response of all sand-capsule composites. The Tung oil bonding could reduce the compressibility by preventing particle breakage of sand during loading. The stabilization mechanism of capsules in carbonate sand with different particle size was further investigated through thermal analysis, CT scan and microscopic analysis, revealing that the compressibility mitigation by capsules depended on the amount of Tung oil release from capsule, which was controlled by the pore structure of sand-capsule composite.
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来源期刊
Powder Technology
Powder Technology 工程技术-工程:化工
CiteScore
9.90
自引率
15.40%
发文量
1047
审稿时长
46 days
期刊介绍: Powder Technology is an International Journal on the Science and Technology of Wet and Dry Particulate Systems. Powder Technology publishes papers on all aspects of the formation of particles and their characterisation and on the study of systems containing particulate solids. No limitation is imposed on the size of the particles, which may range from nanometre scale, as in pigments or aerosols, to that of mined or quarried materials. The following list of topics is not intended to be comprehensive, but rather to indicate typical subjects which fall within the scope of the journal's interests: Formation and synthesis of particles by precipitation and other methods. Modification of particles by agglomeration, coating, comminution and attrition. Characterisation of the size, shape, surface area, pore structure and strength of particles and agglomerates (including the origins and effects of inter particle forces). Packing, failure, flow and permeability of assemblies of particles. Particle-particle interactions and suspension rheology. Handling and processing operations such as slurry flow, fluidization, pneumatic conveying. Interactions between particles and their environment, including delivery of particulate products to the body. Applications of particle technology in production of pharmaceuticals, chemicals, foods, pigments, structural, and functional materials and in environmental and energy related matters. For materials-oriented contributions we are looking for articles revealing the effect of particle/powder characteristics (size, morphology and composition, in that order) on material performance or functionality and, ideally, comparison to any industrial standard.
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