通过CuO@N-doped碳纳米结构增强析氧反应:一个简单的合成和电催化的研究

IF 3.5 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Research on Chemical Intermediates Pub Date : 2024-12-09 DOI:10.1007/s11164-024-05465-5
S. A. T. Shanmuga Priya, Prarthana Srivastava, Gollapalli Veera Satya Srinivas, Sudipta Banerjee, Amanullah Fatehmulla, Animesh Chandra Haldar
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摘要

目前的研究工作主要集中在制备适合于高效和改进氧电解工艺的最佳电催化剂上。采用高效节能、简单经济的低温合成方法制备了介孔CuO@N-doped碳纳米结构。电催化剂的介孔纳米结构类似于多孔结构,多孔结构导致高阳极氧化反应的增加,这反过来又增加了界面之间和催化剂之间的电子电荷转移率。实验分析显示了优异的性能指标,CuO@N-doped碳纳米结构在电流密度为10 mA/cm2时的过电位低至350 mV,塔非斜率为87 mV dec - 1。在实际工业应用中,电催化剂对析氧过程(OER)也有显著的稳定性。
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Enhanced oxygen evolution reaction via CuO@N-doped carbon nanostructures: a facile synthesis and electrocatalytic investigation

The current research work impasses on the fabrication of the best-fitted electrocatalyst for efficient and improved oxygen electrolysis process. The mesoporous CuO@N-doped carbon nanostructures were formulated using energy efficient low temperature synthesis method which is simple as well as economical. The mesoporous nanostructure of the electrocatalyst resembles the porous structure which is responsible for increase in higher anodic oxidative reactions which in turn increases the ratio of the electron charge transfer between the interfaces and of the catalyst as well. Experimental analysis revealed outstanding performance metrics, with the CuO@N-doped carbon nanostructures demonstrating a low overpotential of 350 mV at a current density of 10 mA/cm2 and a Tafel slope of 87 mV dec⁻1. The electrocatalyst was also found to be significantly stable for the oxygen evolution process (OER) in the actual industrial applications.

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来源期刊
CiteScore
5.70
自引率
18.20%
发文量
229
审稿时长
2.6 months
期刊介绍: Research on Chemical Intermediates publishes current research articles and concise dynamic reviews on the properties, structures and reactivities of intermediate species in all the various domains of chemistry. The journal also contains articles in related disciplines such as spectroscopy, molecular biology and biochemistry, atmospheric and environmental sciences, catalysis, photochemistry and photophysics. In addition, special issues dedicated to specific topics in the field are regularly published.
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