离子液体体系从酸性和碱性溶液中萃取铀(ⅵ)

IF 0.5 Q4 CHEMISTRY, MULTIDISCIPLINARY Moscow University Chemistry Bulletin Pub Date : 2025-01-27 DOI:10.3103/S002713142470041X
A. Yu. Fominykh, P. I. Matveev
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引用次数: 0

摘要

本文综述了利用离子液体体系从各种介质中高效、选择性地提取铀(VI)的问题。它审查了目前从乏核燃料溶液中提取铀的技术过程,并指出了其缺点。本文对目前研究的用于铀(ⅵ)萃取的离子液体的主要类型进行了分析和系统整理,包括溶剂、萃取剂和纯离子液体。特别注意的是市售铵离子液体和磷离子液体,它们在从盐酸和碱性介质中提取铀(VI)方面表现出高效率,而在硝酸介质中,四价锕系元素[1]的分布系数最高。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Solvent Extraction of Uranium(VI) from Acidic and Alkaline Solutions Using Ionic Liquid-Based Systems

This review addresses the issue of efficient and selective extraction of uranium(VI) from various media using systems based on ionic liquids. It examines the current technological process for extracting uranium(VI) from spent nuclear fuel solutions and identifies its shortcomings. This review analyzes and systematizes information on the main types of ionic liquids being studied for uranium(VI) extraction, either as solvents, extractants, or in their pure form. Special attention is given to commercially available ammonium and phosphonium ionic liquids, which have demonstrated high efficiency in extracting uranium(VI) from hydrochloric and alkaline media, while in nitric acid media, the highest distribution coefficients are observed for tetravalent actinides [1].

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来源期刊
Moscow University Chemistry Bulletin
Moscow University Chemistry Bulletin CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
1.30
自引率
14.30%
发文量
38
期刊介绍: Moscow University Chemistry Bulletin is a journal that publishes review articles, original research articles, and short communications on various areas of basic and applied research in chemistry, including medical chemistry and pharmacology.
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