{"title":"烯胺酮与s -烷基苯胺盐的i2促进烷基磺酰化/环化:3-烷基磺酰化铬的合成","authors":"Ya-Yu Wang, Ling-Xia Liao, Wen-Tuan Li, Feng-Lin Liu, Xia Li, Dr. Guo-Li Huang","doi":"10.1002/slct.202405579","DOIUrl":null,"url":null,"abstract":"<p>A novel protocol for effective and efficient synthesis of 3-alkylsulfenylated chromones in moderate to good yields via I<sub>2</sub>-promoted alkylsulfenylation/cyclization of enaminones with <i>S</i>-alkyl Bunte salts has been described. This reaction features a broad substrate scope, good functional group tolerance, and metal- and oxidant-free conditions.</p>","PeriodicalId":146,"journal":{"name":"ChemistrySelect","volume":"10 5","pages":""},"PeriodicalIF":2.0000,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"I2-Promoted Alkylsulfenylation/Cyclization of Enaminones with S-Alkyl Bunte Salts: Synthesis of 3-Alkylsulfenylated Chromones\",\"authors\":\"Ya-Yu Wang, Ling-Xia Liao, Wen-Tuan Li, Feng-Lin Liu, Xia Li, Dr. Guo-Li Huang\",\"doi\":\"10.1002/slct.202405579\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A novel protocol for effective and efficient synthesis of 3-alkylsulfenylated chromones in moderate to good yields via I<sub>2</sub>-promoted alkylsulfenylation/cyclization of enaminones with <i>S</i>-alkyl Bunte salts has been described. This reaction features a broad substrate scope, good functional group tolerance, and metal- and oxidant-free conditions.</p>\",\"PeriodicalId\":146,\"journal\":{\"name\":\"ChemistrySelect\",\"volume\":\"10 5\",\"pages\":\"\"},\"PeriodicalIF\":2.0000,\"publicationDate\":\"2025-02-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemistrySelect\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202405579\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemistrySelect","FirstCategoryId":"92","ListUrlMain":"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202405579","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
I2-Promoted Alkylsulfenylation/Cyclization of Enaminones with S-Alkyl Bunte Salts: Synthesis of 3-Alkylsulfenylated Chromones
A novel protocol for effective and efficient synthesis of 3-alkylsulfenylated chromones in moderate to good yields via I2-promoted alkylsulfenylation/cyclization of enaminones with S-alkyl Bunte salts has been described. This reaction features a broad substrate scope, good functional group tolerance, and metal- and oxidant-free conditions.
期刊介绍:
ChemistrySelect is the latest journal from ChemPubSoc Europe and Wiley-VCH. It offers researchers a quality society-owned journal in which to publish their work in all areas of chemistry. Manuscripts are evaluated by active researchers to ensure they add meaningfully to the scientific literature, and those accepted are processed quickly to ensure rapid online publication.