Chaolin Wu, Yanlong Xie, Dr. Jiliang Song, Prof. Xiujuan Feng, Siqi Jian, Wenchao Lu, Jiuzhen Zhu, Prof. Yoshinori Yamamoto, Prof. Ming Bao
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Caboxylative Coupling of N-(Arylmethyl)sulfonimides with Allyltributylstannane Catalyzed by Palladium Nanoparticles Involving Benzylic C−N Cleavage
The palladium-catalyzed three-component coupling of aryl (hetero) methylsulfonamide, allyltributyltin and carbon dioxide (carboxylative Stille coupling reaction) was successfully conduced to produce β,γ-unsaturated esters in satisfactory to good yields. The reaction was carried out under mild conditions by using in situ generated palladium nanoparticles as catalyst through the formation of π-allylpalladium sulfonamide intermediates in the presence of tetrabutylammonium bromide (TBAB).
期刊介绍：
Organic chemistry is the fundamental science that stands at the heart of chemistry, biology, and materials science. Research in these areas is vigorous and truly international, with three major regions making almost equal contributions: America, Europe and Asia. Asia now has its own top international organic chemistry journal—the Asian Journal of Organic Chemistry (AsianJOC)
The AsianJOC is designed to be a top-ranked international research journal and publishes primary research as well as critical secondary information from authors across the world. The journal covers organic chemistry in its entirety. Authors and readers come from academia, the chemical industry, and government laboratories.
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