离网和远程电力应用的机械可充电锌空气电池

Future Batteries Pub Date : 2025-02-01 Epub Date: 2025-01-06 DOI:10.1016/j.fub.2025.100029
B. Aremo, S.I. Oyinseye, I.E. Akinwole, S.A. Ayodeji, G.F. Abass
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引用次数: 0

摘要

由于偏远和农村地区没有电网供电,对二次电池的充电提出了挑战。机械充电的锌空气电池可以缓解这个问题。这项工作报告了一种紧凑的,机械可充电的锌-空气电池,建立在电铸平面镍网集流器的框架周围。电池性能在寿命和极化研究中进行了评估。采用CAD和3D打印技术对平面紧凑电池底盘进行了设计和制作。锌板和4摩尔KOH分别作为阳极和电解质。阴极是一个吸气式气体扩散电极,压入镍网集流器的开口中。每个电池电极的表面积为400 mm2,而OCV为1.32 V。从极化研究来看,在1.0 V的电压下,可以在电压保持稳定的情况下对电池施加710 Ω(或更高)的负载。寿命测试还表明,当为微型直流电机供电6 小时时,极化电位仅最低限度地下降。
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Mechanically rechargeable zinc-air battery for off-grid and remote power applications
Non-availability of grid-electricity in remote and rural areas presents a challenge for recharging secondary batteries. Mechanically rechargeable zinc-air batteries should mitigate this problem. This work reports a compact, mechanically rechargeable zinc-air battery built around the framework of an electroformed planar nickel mesh current collector. The battery performance was evaluated in longevity and polarization studies. Design and production of the planar, compact battery chassis was done using CAD and 3D printing. A zinc plate and 4-molar KOH were used for the anode and electrolyte respectively. The cathode is an air-breathing gas diffusion electrode that is pressed into the openings of the nickel mesh current collector. The battery electrodes each have a surface area of 400 mm2 while the OCV was 1.32 V. From the polarization studies, at a voltage of 1.0 V, a load of 710 Ω (or higher) can be imposed on the cell with the voltage remaining stable. The longevity test also shows that whilst powering a mini-DC motor for 6 hours, the polarisation potential depreciated only minimally.
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