通过圆顶状变截面通道提高PEMFC性能:传质和功率密度优化研究

IF 2.4 4区 化学 Q4 ELECTROCHEMISTRY International Journal of Electrochemical Science Pub Date : 2025-01-01 Epub Date: 2024-12-16 DOI:10.1016/j.ijoes.2024.100920
Keke Liu , Yongfeng Liu , Qiwo Han , Pucheng Pei , Lu Zhang , Hua Sun
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引用次数: 0

摘要

优化双极板嵌入通道的结构对提高质子交换膜燃料电池(PEMFC)的传质和功率密度具有重要意义。本文受穹顶结构的启发,提出了一种结合突起和传统平行通道(CPC)的新型变截面通道(CN-17)来提高PEMFC的性能。通过改变分支通道的数量,设计了一系列新型通道(dvcc),并通过实验数据验证了三维计算流体力学模型进行了详细的性能研究。Python代码用于计算肋面积比,并对电流密度进行统计分析。结果表明,与CPC相比,CN-17的最大电流密度提高了8.31 %,最大功率密度提高了7.36 %。研究还发现,dvcc加速了反应气体的流动,促进了氧进入催化剂层(CL),并且在GDL/CL界面处氧和电流密度分布均匀。此外,随着分支通道数量的增加,PEMFC的性能也有所提高。具有19个分支通道的DVCC (CN-19)表现出最好的性能。
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Enhancing PEMFC performance through dome-like variable cross-section channels: A study on mass transfer and power density optimization
The structural optimization of channel embedded in bipolar plate is of great significance for improving the mass transfer and power density of proton exchange membrane fuel cell (PEMFC). In this paper, inspired by the dome-like architecture, a novel variable cross-section channel (CN-17) combining protrusions and conventional parallel channel (CPC) is proposed to enhance the performance of PEMFC. By changing the number of branch channels, a series of novel channels (DVCCs) are also designed, and the detailed performance study is conducted by a three-dimensional (3D) computational fluid dynamics model verified by the experiment data. Python code is used for calculating the rib area ratio and conducting statistical analysis of current density. It is found that CN-17 demonstrates an 8.31 % increase in maximum current density and a 7.36 % increase in maximum power density compared to CPC. It is also found that DVCCs accelerate the flow of reactive gas, promote the oxygen to enter the catalyst layer (CL), and uniform distribution of oxygen and current density at the GDL/CL interface. Furthermore, as the number of branch channels increases, the performance of PEMFC improves. The DVCC with 19 branch channels (CN-19) exhibits the best performance.
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来源期刊
CiteScore
3.00
自引率
20.00%
发文量
714
审稿时长
2.6 months
期刊介绍: International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry
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