Song Pan, Chong Chen, Qing-Wen Liang, Ai-Quan Jia, Qian-Feng Zhang
{"title":"两种双核硫桥聚伞烷-氟二硫代磷酸钌的合成、结构及光催化性能","authors":"Song Pan, Chong Chen, Qing-Wen Liang, Ai-Quan Jia, Qian-Feng Zhang","doi":"10.1016/j.jorganchem.2024.123481","DOIUrl":null,"url":null,"abstract":"<div><div>A binuclear complex [(<em>η<sup>6</sup></em>-<em>p</em>-cymene)<sub>2</sub>Ru<sub>2</sub>Cl<sub>2</sub>(S<sub>2</sub>POF)] (<strong>1</strong>) was generated by combining a binuclear ruthenium precursor [(<em>η<sup>6</sup></em>-<em>p</em>-cymene)RuCl<sub>2</sub>]<sub>2</sub> with an equivalent amount of [N<sup>n</sup>Pr<sub>4</sub>]<sub>2</sub>[S<sub>5</sub>P<sub>2</sub>F<sub>2</sub>] in dichloromethane at room temperature. Treatment of [(<em>η<sup>6</sup></em>-<em>p</em>-cymene)RuCl<sub>2</sub>]<sub>2</sub> with two equivalents of [N<sup>n</sup>Pr<sub>4</sub>]<sub>2</sub>[S<sub>5</sub>P<sub>2</sub>F<sub>2</sub>] in dichloromethane at reflux in the presence of AgNO<sub>3</sub> led to isolation of a binuclear ruthenium complex [(<em>η<sup>6</sup></em>-<em>p</em>-cymene)Ru(S<sub>2</sub>POF)]<sub>2</sub> (<strong>2</strong>). Complexes <strong>1</strong> and <strong>2</strong> were characterized by IR, <em>multi</em>-NMR (<sup>1</sup>H, <sup>31</sup>P, <sup>19</sup>F) and UV–vis spectroscopies. The structures of complexes <strong>1</strong> and <strong>2</strong> have been established by single-crystal X-ray crystallography. In addition, the photocatalytic properties of complex <strong>2</strong> for hydrogen production from water splitting under visible light were also investigated.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1025 ","pages":"Article 123481"},"PeriodicalIF":2.1000,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, structures and photocatalytic properties of two binuclear sulfur-bridged cymene-ruthenium fluorodithiophosphates\",\"authors\":\"Song Pan, Chong Chen, Qing-Wen Liang, Ai-Quan Jia, Qian-Feng Zhang\",\"doi\":\"10.1016/j.jorganchem.2024.123481\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A binuclear complex [(<em>η<sup>6</sup></em>-<em>p</em>-cymene)<sub>2</sub>Ru<sub>2</sub>Cl<sub>2</sub>(S<sub>2</sub>POF)] (<strong>1</strong>) was generated by combining a binuclear ruthenium precursor [(<em>η<sup>6</sup></em>-<em>p</em>-cymene)RuCl<sub>2</sub>]<sub>2</sub> with an equivalent amount of [N<sup>n</sup>Pr<sub>4</sub>]<sub>2</sub>[S<sub>5</sub>P<sub>2</sub>F<sub>2</sub>] in dichloromethane at room temperature. Treatment of [(<em>η<sup>6</sup></em>-<em>p</em>-cymene)RuCl<sub>2</sub>]<sub>2</sub> with two equivalents of [N<sup>n</sup>Pr<sub>4</sub>]<sub>2</sub>[S<sub>5</sub>P<sub>2</sub>F<sub>2</sub>] in dichloromethane at reflux in the presence of AgNO<sub>3</sub> led to isolation of a binuclear ruthenium complex [(<em>η<sup>6</sup></em>-<em>p</em>-cymene)Ru(S<sub>2</sub>POF)]<sub>2</sub> (<strong>2</strong>). Complexes <strong>1</strong> and <strong>2</strong> were characterized by IR, <em>multi</em>-NMR (<sup>1</sup>H, <sup>31</sup>P, <sup>19</sup>F) and UV–vis spectroscopies. The structures of complexes <strong>1</strong> and <strong>2</strong> have been established by single-crystal X-ray crystallography. In addition, the photocatalytic properties of complex <strong>2</strong> for hydrogen production from water splitting under visible light were also investigated.</div></div>\",\"PeriodicalId\":374,\"journal\":{\"name\":\"Journal of Organometallic Chemistry\",\"volume\":\"1025 \",\"pages\":\"Article 123481\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2025-02-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Organometallic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0022328X24004765\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/12/15 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Organometallic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022328X24004765","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/12/15 0:00:00","PubModel":"Epub","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Synthesis, structures and photocatalytic properties of two binuclear sulfur-bridged cymene-ruthenium fluorodithiophosphates
A binuclear complex [(η6-p-cymene)2Ru2Cl2(S2POF)] (1) was generated by combining a binuclear ruthenium precursor [(η6-p-cymene)RuCl2]2 with an equivalent amount of [NnPr4]2[S5P2F2] in dichloromethane at room temperature. Treatment of [(η6-p-cymene)RuCl2]2 with two equivalents of [NnPr4]2[S5P2F2] in dichloromethane at reflux in the presence of AgNO3 led to isolation of a binuclear ruthenium complex [(η6-p-cymene)Ru(S2POF)]2 (2). Complexes 1 and 2 were characterized by IR, multi-NMR (1H, 31P, 19F) and UV–vis spectroscopies. The structures of complexes 1 and 2 have been established by single-crystal X-ray crystallography. In addition, the photocatalytic properties of complex 2 for hydrogen production from water splitting under visible light were also investigated.
期刊介绍：
The Journal of Organometallic Chemistry targets original papers dealing with theoretical aspects, structural chemistry, synthesis, physical and chemical properties (including reaction mechanisms), and practical applications of organometallic compounds.
Organometallic compounds are defined as compounds that contain metal - carbon bonds. The term metal includes all alkali and alkaline earth metals, all transition metals and the lanthanides and actinides in the Periodic Table. Metalloids including the elements in Group 13 and the heavier members of the Groups 14 - 16 are also included. The term chemistry includes syntheses, characterizations and reaction chemistry of all such compounds. Research reports based on use of organometallic complexes in bioorganometallic chemistry, medicine, material sciences, homogeneous catalysis and energy conversion are also welcome.
The scope of the journal has been enlarged to encompass important research on organometallic complexes in bioorganometallic chemistry and material sciences, and of heavier main group elements in organometallic chemistry. The journal also publishes review articles, short communications and notes.
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