超声辅助铜催化硝基化合物的s-芳基化-杂烯加合物

IF 1.6 4区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-09-02 Epub Date: 2024-11-09 DOI:10.1080/10426507.2024.2427135
Manijeh Nematpour
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引用次数: 0

摘要

以CuI为催化剂,以K2CO3为碱,在室温下超声辐照下成功地实现了硝基化合物-杂烯加合物的s-芳基化反应。使用简单易得的起始材料,不需要柱层析,温和的铜催化反应条件,良好的产率(70-89%),应用声化学方法,反应时间短是该方案的显著特点。
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Ultrasound-assisted, copper-catalyzed S-arylation of nitro compounds-heterocumulene adducts
S-Arylation of nitro compounds-heterocumulene adducts with CuI as the catalyst, K2CO3 as the base, and highly efficient was successfully implemented without the help of an additional ligand under ultrasound irradiation in MeCN at room temperature. The use of simple and readily available starting materials, no need for column chromatography, mild copper-catalytic reaction conditions, good yields (70–89%), application of the sonochemical methodology, and short reaction times are remarkable specifications of this protocol.
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来源期刊
CiteScore
2.60
自引率
7.70%
发文量
103
审稿时长
2.1 months
期刊介绍: Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.
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