在磁场作用下,利用活化过硫酸盐和二硫代盐的组合去除罗丹明B染料的新方法

IF 4.2 3区 工程技术 Q3 ENERGY & FUELS Chemical Engineering and Processing - Process Intensification Pub Date : 2025-03-01 Epub Date: 2025-01-06 DOI:10.1016/j.cep.2025.110160
Ahmad Rajabizadeh , Hossein Abdipour , Hossein Jafari Mansoorian
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引用次数: 0

摘要

考虑到水资源短缺危机,从纺织废水中去除染料对保护健康和环境至关重要。回收这些水对于可持续的资源管理至关重要。研究了磁场作用下活化二亚铁和过硫酸盐对纺织废水中罗丹明B的降解和矿化效果。在实验室尺度上评估了pH(3-10)、过硫酸盐+二硫代盐浓度(5-20 mg/L)、磁场强度(1-4 A)、罗丹明B初始浓度(10-100 mg/L)和接触时间(15-120 min)等参数。采用田口模型确定最佳工艺条件:pH=7,过硫酸盐浓度为20 mg/L,磁场强度为4 A,反应时间为90 min,罗丹明B初始浓度为50 mg/L。对罗丹明B的去除率为15.90%,对TOC的破坏率为90%。反应动力学符合拟二阶模型(R²= 0.9983)。研究结果表明,增加磁场强度可使效率提高36.6%。本研究的结果是有希望的,并证明了该工艺在纺织和印染工业中的潜在应用。因此,考虑到与废水处理有关的任何限制,需要进行经济可行性和成本效益分析。
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A new approach for the elimination of Rhodamine B dye using a combination of activated persulfate and dithionite in the presence of magnetic fields
Considering the water shortage crisis, removing dye from textile wastewater is crucial to protect health and the environment. Recycling this water is vital for sustainable resource management. In the present study, the efficiency of degradation and mineralization of rhodamine B from textile industry wastewater using activated dithionite and persulfate with the aid of a magnetic field was investigated. Various parameters such as pH (3–10), Persulfate+ dithionite concentration (5–20 mg/L), magnetic field intensity (1–4 A), initial rhodamine B concentration (10–100 mg/L), and contact time (15–120 min) were evaluated on a laboratory scale. The optimal conditions were determined by the Taguchi model, which were pH=7, persulfate concentration of 20 mg/L, magnetic field intensity of 4 A, reaction time of 90 min, and initial rhodamine B concentration of 50 mg/L. The rhodamine B removal efficiency and TOC destruction efficiency were obtained as 15.90 % and 90 %, respectively. The kinetics of the process followed a pseudo-second-order model (R² = 0.9983). The results of this study show that increasing the magnetic field intensity resulted in a 36.6 % improvement in efficiency. The findings of this study are promising and justify the potential application of this process in the textile and dyeing industries. Therefore, economic feasibility and cost-benefit analysis are required, taking into account any limitations related to wastewater treatment.
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来源期刊
CiteScore
7.80
自引率
9.30%
发文量
408
审稿时长
49 days
期刊介绍: Chemical Engineering and Processing: Process Intensification is intended for practicing researchers in industry and academia, working in the field of Process Engineering and related to the subject of Process Intensification.Articles published in the Journal demonstrate how novel discoveries, developments and theories in the field of Process Engineering and in particular Process Intensification may be used for analysis and design of innovative equipment and processing methods with substantially improved sustainability, efficiency and environmental performance.
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