Boshuo Shi , Bo Wang , Yujiang Wang , Jianshe Chen , Binchuan Li , Qing Han , Kuiren Liu , Shicheng Wei
{"title":"高温机械化学技术合成的石墨插层ZnFe2O4/C复合材料的微波吸收性能","authors":"Boshuo Shi , Bo Wang , Yujiang Wang , Jianshe Chen , Binchuan Li , Qing Han , Kuiren Liu , Shicheng Wei","doi":"10.1016/j.materresbull.2024.113263","DOIUrl":null,"url":null,"abstract":"<div><div>Constructing the magnetic/dielectric synergistic effect between ferrite and carbon materials is an important strategy to obtain microwave absorbers. ZnFe<sub>2</sub>O<sub>4</sub> and graphite intercalation compounds (GICs) are creatively combined by high-temperature mechanochemical technology. The results show that ZnFe<sub>2</sub>O<sub>4</sub> is attached to the surface and pores of graphite with special three-dimensional structure, the propagation path of microwaves in the composites can be extended, and polarization effects and magnetic loss of ZnFe<sub>2</sub>O<sub>4</sub>/C composites can be effectively enhanced. When the addition amounts of GICs is 10 wt%, the reflection loss (RL) of ZnFe<sub>2</sub>O<sub>4</sub>/C composite reaches −41.49 dB at a thickness of 4.5 mm, and the effective absorption bandwidth (EAB) reaches 3.92 GHz at a thickness of only 1.5 mm. This work provides a new idea for the synthesis of ZnFe<sub>2</sub>O<sub>4</sub>/C microwave absorbers agent by high-temperature mechanochemical technology.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"184 ","pages":"Article 113263"},"PeriodicalIF":5.7000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The microwave absorption performance of ZnFe2O4/C composites synthesized by high-temperature mechanochemical technology with graphite intercalation compounds\",\"authors\":\"Boshuo Shi , Bo Wang , Yujiang Wang , Jianshe Chen , Binchuan Li , Qing Han , Kuiren Liu , Shicheng Wei\",\"doi\":\"10.1016/j.materresbull.2024.113263\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Constructing the magnetic/dielectric synergistic effect between ferrite and carbon materials is an important strategy to obtain microwave absorbers. ZnFe<sub>2</sub>O<sub>4</sub> and graphite intercalation compounds (GICs) are creatively combined by high-temperature mechanochemical technology. The results show that ZnFe<sub>2</sub>O<sub>4</sub> is attached to the surface and pores of graphite with special three-dimensional structure, the propagation path of microwaves in the composites can be extended, and polarization effects and magnetic loss of ZnFe<sub>2</sub>O<sub>4</sub>/C composites can be effectively enhanced. When the addition amounts of GICs is 10 wt%, the reflection loss (RL) of ZnFe<sub>2</sub>O<sub>4</sub>/C composite reaches −41.49 dB at a thickness of 4.5 mm, and the effective absorption bandwidth (EAB) reaches 3.92 GHz at a thickness of only 1.5 mm. This work provides a new idea for the synthesis of ZnFe<sub>2</sub>O<sub>4</sub>/C microwave absorbers agent by high-temperature mechanochemical technology.</div></div>\",\"PeriodicalId\":18265,\"journal\":{\"name\":\"Materials Research Bulletin\",\"volume\":\"184 \",\"pages\":\"Article 113263\"},\"PeriodicalIF\":5.7000,\"publicationDate\":\"2025-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Research Bulletin\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0025540824005919\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/12/12 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Research Bulletin","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0025540824005919","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/12/12 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
The microwave absorption performance of ZnFe2O4/C composites synthesized by high-temperature mechanochemical technology with graphite intercalation compounds
Constructing the magnetic/dielectric synergistic effect between ferrite and carbon materials is an important strategy to obtain microwave absorbers. ZnFe2O4 and graphite intercalation compounds (GICs) are creatively combined by high-temperature mechanochemical technology. The results show that ZnFe2O4 is attached to the surface and pores of graphite with special three-dimensional structure, the propagation path of microwaves in the composites can be extended, and polarization effects and magnetic loss of ZnFe2O4/C composites can be effectively enhanced. When the addition amounts of GICs is 10 wt%, the reflection loss (RL) of ZnFe2O4/C composite reaches −41.49 dB at a thickness of 4.5 mm, and the effective absorption bandwidth (EAB) reaches 3.92 GHz at a thickness of only 1.5 mm. This work provides a new idea for the synthesis of ZnFe2O4/C microwave absorbers agent by high-temperature mechanochemical technology.
期刊介绍:
Materials Research Bulletin is an international journal reporting high-impact research on processing-structure-property relationships in functional materials and nanomaterials with interesting electronic, magnetic, optical, thermal, mechanical or catalytic properties. Papers purely on thermodynamics or theoretical calculations (e.g., density functional theory) do not fall within the scope of the journal unless they also demonstrate a clear link to physical properties. Topics covered include functional materials (e.g., dielectrics, pyroelectrics, piezoelectrics, ferroelectrics, relaxors, thermoelectrics, etc.); electrochemistry and solid-state ionics (e.g., photovoltaics, batteries, sensors, and fuel cells); nanomaterials, graphene, and nanocomposites; luminescence and photocatalysis; crystal-structure and defect-structure analysis; novel electronics; non-crystalline solids; flexible electronics; protein-material interactions; and polymeric ion-exchange membranes.