高温机械化学技术合成的石墨插层ZnFe2O4/C复合材料的微波吸收性能

IF 5.7 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Research Bulletin Pub Date : 2025-04-01 Epub Date: 2024-12-12 DOI:10.1016/j.materresbull.2024.113263
Boshuo Shi , Bo Wang , Yujiang Wang , Jianshe Chen , Binchuan Li , Qing Han , Kuiren Liu , Shicheng Wei
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引用次数: 0

摘要

构建铁氧体与碳材料之间的磁/介电协同效应是获得微波吸收材料的重要策略。采用高温机械化学技术,创造性地将ZnFe2O4与石墨插层化合物(gic)结合在一起。结果表明:ZnFe2O4以特殊的三维结构附着在石墨表面和孔隙上,扩展了微波在复合材料中的传播路径,有效增强了ZnFe2O4/C复合材料的极化效应和磁损耗;当GICs添加量为10 wt%时,在厚度为4.5 mm时,ZnFe2O4/C复合材料的反射损耗(RL)达到- 41.49 dB,在厚度仅为1.5 mm时,有效吸收带宽(EAB)达到3.92 GHz。本研究为高温机械化学技术合成ZnFe2O4/C微波吸收剂提供了新的思路。
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The microwave absorption performance of ZnFe2O4/C composites synthesized by high-temperature mechanochemical technology with graphite intercalation compounds
Constructing the magnetic/dielectric synergistic effect between ferrite and carbon materials is an important strategy to obtain microwave absorbers. ZnFe2O4 and graphite intercalation compounds (GICs) are creatively combined by high-temperature mechanochemical technology. The results show that ZnFe2O4 is attached to the surface and pores of graphite with special three-dimensional structure, the propagation path of microwaves in the composites can be extended, and polarization effects and magnetic loss of ZnFe2O4/C composites can be effectively enhanced. When the addition amounts of GICs is 10 wt%, the reflection loss (RL) of ZnFe2O4/C composite reaches −41.49 dB at a thickness of 4.5 mm, and the effective absorption bandwidth (EAB) reaches 3.92 GHz at a thickness of only 1.5 mm. This work provides a new idea for the synthesis of ZnFe2O4/C microwave absorbers agent by high-temperature mechanochemical technology.
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来源期刊
Materials Research Bulletin
Materials Research Bulletin 工程技术-材料科学:综合
CiteScore
9.80
自引率
5.60%
发文量
372
审稿时长
42 days
期刊介绍: Materials Research Bulletin is an international journal reporting high-impact research on processing-structure-property relationships in functional materials and nanomaterials with interesting electronic, magnetic, optical, thermal, mechanical or catalytic properties. Papers purely on thermodynamics or theoretical calculations (e.g., density functional theory) do not fall within the scope of the journal unless they also demonstrate a clear link to physical properties. Topics covered include functional materials (e.g., dielectrics, pyroelectrics, piezoelectrics, ferroelectrics, relaxors, thermoelectrics, etc.); electrochemistry and solid-state ionics (e.g., photovoltaics, batteries, sensors, and fuel cells); nanomaterials, graphene, and nanocomposites; luminescence and photocatalysis; crystal-structure and defect-structure analysis; novel electronics; non-crystalline solids; flexible electronics; protein-material interactions; and polymeric ion-exchange membranes.
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