滇中粘土型锂矿工艺矿物学研究

IF 6.3 3区 工程技术 Q1 ENGINEERING, CHEMICAL Journal of the Taiwan Institute of Chemical Engineers Pub Date : 2025-03-01 Epub Date: 2025-01-03 DOI:10.1016/j.jtice.2024.105900
Ruiqi Xie , Xiong Tong , Xian Xie , Qiang Song , Shuaipeng Ren , Xun Wang , Zhihui Zhao , Yang Liu
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引用次数: 0

摘要

滇中地区发现的粘土型锂资源因其储量大、地理位置优越,将成为未来重要的锂资源。工艺矿物学特征对粘土型锂资源的分离提取至关重要。为此,本文对滇中地区粘土型锂矿的化学成分、矿物组成、矿物学特征、主要矿物的分布粒度及共生关系进行了分析。方法采用x射线荧光光谱(XPS)、x射线衍射分析(XRD)、化学多元素分析、热分析、酸溶试验、显微镜、矿物解离分析仪(MLA)等方法。此外,还首次在显微镜下人工选择了富集的矿石样品。采用化学多元素分析和XRD定量分析研究了锂的赋存状态。结果表明,该矿石由16种矿物组成,锂主要以沸石形式存在。由于分布粒度和共生关系的关系,需要极细的磨矿粒度来进行烹调石的分离。脉石主要为一水硬石、薄水铝石和高岭石。因此,研究它们对锂萃取的影响,对于开发选择性焙烧助剂和浸出剂具有重要意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Study on process mineralogy of clay-type lithium ore in central region of Yunnan province

Background

The clay-type lithium resource founded in central region of Yunnan province will become a crucial lithium resource in the future because of its large reserves and superior geographical location. The technological mineralogical characteristics are extremely important for clay-type lithium resource separation and extraction. Therefore, in this paper, the chemical composition, mineral composition, mineralogical characteristics, distribution size and symbiotic relationship of main minerals of clay-type lithium ore in the central region of Yunnan Province were analyzed.

Methods

The X-ray fluorescence spectrum (XPS), X-ray diffraction analysis (XRD), chemical multi-element analysis, thermal analysis, acid dissolution test, microscope, and mineral liberation analyser (MLA) were used. In addition, for the first time, the enriched ore samples were manually selected under the microscope. The occurrence state of lithium was investigated by chemical multi-element analysis and XRD quantitative analysis.

Significant findings

The results revealed that the ore was composed of 16 kinds of minerals and lithium exists mainly in the form of cookeite. Due to the distribution size and symbiotic relationship, extremely fine grinding particle size is required for cookeite separation. Meanwhile, the main gangues are diaspore, boehmite and kaolinite. Therefore, exploring the effects of them on the lithium extraction is important for the development of selective roasting additives and leaching reagents.
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来源期刊
CiteScore
9.10
自引率
14.00%
发文量
362
审稿时长
35 days
期刊介绍: Journal of the Taiwan Institute of Chemical Engineers (formerly known as Journal of the Chinese Institute of Chemical Engineers) publishes original works, from fundamental principles to practical applications, in the broad field of chemical engineering with special focus on three aspects: Chemical and Biomolecular Science and Technology, Energy and Environmental Science and Technology, and Materials Science and Technology. Authors should choose for their manuscript an appropriate aspect section and a few related classifications when submitting to the journal online.
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