清洁燃料采用环保型氧化脱硫工艺的最新趋势

Cleaner Chemical Engineering Pub Date : 2025-12-01 Epub Date: 2024-12-19 DOI:10.1016/j.clce.2024.100140
S. Said, S. Mikhail, M. Riad
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引用次数: 0

摘要

燃料油的大量消耗造成了环境污染,减少有毒含硫化合物是必要的。环境修复获得清洁脱硫技术;氧化脱硫(ODS)工艺因其反应条件温和、无需加氢、脱硫性能显著等优点,成为生产含硫清洁燃料的研究热点。本文综述了金属有机骨架/金属氧化物复合材料、多金属氧酸盐、钛氧化物和钼氧化物等材料的研究进展。讨论了ODS催化剂性能与性能之间的内在联系。综述了萃取、光催化、吸附、超声和混合等其他耗氧物质辅助工艺的应用。所提出的见解将有助于开发更准确和有效的清洁燃料生产方法,从而有助于保护人类健康和环境。从混合辅助脱硫工艺等方法学角度为今后的研究和开发提供指导。最后,提出了该技术进一步成熟所需要进行的工作,为实际燃料生产清洁燃料的高效氧化脱硫技术提供了可行的前景。
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Recent trends for clean fuel using environmental protecting oxidative desulfurization process
The tremendous consumption of fuel oil causes the environmental pollution and it is necessary to curtail toxic sulfur compounds. The environmental remediation acquires clean desulfurization technology; oxidative desulfurization (ODS) process is intensively studied to produce sulfur clean fuels due to its mild reaction conditions, no hydrogen need and its notable desulfurization performances. This work emphasizes a comprehensive review on the recent finding in catalytic ODS including recently developed materials as metal organic framework/metal oxide composite, polyoxometalate, titanium and molybdenum oxides. The essential link between the catalyst properties and performances in ODS are discussed. The utilization of other ODS assisted processes like extractive, photo-catalytic, adsorptive, ultrasonic and mixing are also reviewed. The insights presented will aid in the development of more accurate and efficient methods for clean fuel production, thereby helping to protect human health and the environment. The review provides guidance from a methodology perspective like mixing assisted desulfurization process for future research and development. Finally, the required future works to mature this technology are suggested providing feasible outlook in efficient oxidative desulfurization technologies for clean fuel production from real fuel.
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