白头翁。叶片提取物作为碳钢在盐酸环境中的缓蚀剂

IF 5.9 3区 工程技术 Q1 CHEMISTRY, MULTIDISCIPLINARY Journal of Industrial and Engineering Chemistry Pub Date : 2025-03-25 Epub Date: 2024-08-30 DOI:10.1016/j.jiec.2024.08.054
Khang Duy Huu Nguyen , Tran Dinh Manh , Lien Thi Phuong Nguyen , Dao Thanh Vu , Kim Long Duong Ngo
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摘要

本文主要研究了合欢的缓蚀性能。碳钢叶片提取物(SPWE)在1.0 M盐酸培养基中。电化学方法表明,在腐蚀溶液中加入2000 ppm的提取物,其缓蚀效率为94.65±0.94%。此外,表面分析结果表明,在没有缓蚀剂的情况下,钢表面腐蚀严重,但腐蚀密度缓慢,将SPWE应用于腐蚀环境后,表面形成一层膜。本研究对多酚、类黄酮、生物碱、单宁等化合物在碳钢表面的化学和物理吸附形成的膜进行了定性和定量分析。值得注意的是,随着浸泡时间和反应温度的增加,分子的解吸作用明显,反映了物理吸附的特征。然而,SPWE的缓蚀效率仍然有效,特别是在25-35℃的温度范围内。因此,本研究为碳钢在1.0 M盐酸酸性环境中提供了一种有效的缓蚀剂,可以添加到缓蚀剂体系中。
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Syzygium polyanthum (Wight) Walp. leaf extract as a sustainable corrosion inhibitor for carbon steel in hydrochloric acidic environment
This study focuses on an investigation of the corrosion inhibition behavior of Syzygium polyanthum (Wight) Walp. leaf extract (SPWE) of carbon steel in 1.0 M hydrochloric acid medium. Electrochemical methods demonstrated a corrosion inhibition efficiency of 94.65 ± 0.94 % when 2000 ppm extract is added to the corrosive solution. Furthermore, surface analysis results indicated that with the absence of an inhibitor, the steel surface suffered severe corrosion, while the corrosion density was slow, and a film was observed on the surface after applying the SPWE into a corrosive environment. The film formed by the chemical and physical adsorption of compounds such as polyphenol, flavonoid, alkaloid, and tannin onto the carbon steel surface has been qualitatively and quantitatively analyzed in this study. Notably, increased immersion time and reaction temperature led to significant desorption of molecules, reflecting characteristic of physical adsorption. However, the corrosion inhibition efficiency of SPWE remained effective, particularly within the temperature range of 25–35 °C. Therefore, this study provides an efficient inhibitor for carbon steel corrosion in 1.0 M hydrochloric acidic environment that could be possibly added to the corrosion inhibitor system.
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来源期刊
CiteScore
10.40
自引率
6.60%
发文量
639
审稿时长
29 days
期刊介绍: Journal of Industrial and Engineering Chemistry is published monthly in English by the Korean Society of Industrial and Engineering Chemistry. JIEC brings together multidisciplinary interests in one journal and is to disseminate information on all aspects of research and development in industrial and engineering chemistry. Contributions in the form of research articles, short communications, notes and reviews are considered for publication. The editors welcome original contributions that have not been and are not to be published elsewhere. Instruction to authors and a manuscript submissions form are printed at the end of each issue. Bulk reprints of individual articles can be ordered. This publication is partially supported by Korea Research Foundation and the Korean Federation of Science and Technology Societies.
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