Al-Zr-Sc导体合金在长期高温暴露中的热稳定性

IF 6.6 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Materials Research and Technology-Jmr&t Pub Date : 2025-03-01 Epub Date: 2025-01-07 DOI:10.1016/j.jmrt.2025.01.043
Quan Shao , Emad M. Elgallad , Alexandre Maltais , X.-Grant Chen
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引用次数: 0

摘要

通过铸造、热轧、热处理和冷拉丝加工,制备了Zr含量为0.1 ~ 0.18 wt%和Sc含量为0.1 ~ 0.15 wt%的4种Al-Zr-Sc导体合金。利用扫描电镜、透射电镜和电子后向散射衍射技术对合金丝的力学性能和电导率进行了评价,并对合金丝的显微组织进行了表征。在310、350和400℃的高温下,对合金的热稳定性进行了系统评估,结果表明,4种Al-Zr-Sc合金丝的极限抗拉强度(UTSs)达到206 ~ 214 MPa,电导率为57% ~ 57.5%。四种合金丝均被大量的Al3(Sc,Zr)纳米沉淀物强化。随着Zr或Sc含量的增加,UTS仅略有增加,表明Zr和Sc含量对拉伸强度和电导率的影响较小。值得注意的是,在310°C下热暴露1000小时后,四种合金丝的抗拉强度没有明显降低,晶粒变形组织也没有发生变化。在350°C下热暴露200小时后,四种合金丝仍然表现出优异的热稳定性。在350°C和400°C下长时间暴露,合金丝变得不稳定。高zr含量的Al-0.18Zr-0.1Sc和Al-0.18Zr-0.15Sc合金在350℃和400℃长期热暴露后表现出较好的热稳定性。本文研究了Al - zr - sc导体合金在极端条件下的热稳定性,为耐热铝导体导线的工业应用提供了有价值的参考。
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Thermal stability of Al–Zr-Sc conductor alloys during long-term elevated-temperature exposures
Four Al–Zr-Sc conductor alloys with 0.1–0.18 wt% Zr and 0.1–0.15 wt% Sc were processed through casting, hot rolling, heat treatments, and cold wire drawing. The mechanical properties and electrical conductivities of the alloy wires were evaluated, and the microstructures were characterized using scanning electron microscopy, transmission electron microscopy, and electron backscattering diffraction techniques. The thermal stabilities of these alloys were systematically assessed during thermal exposures at 310, 350, and 400 °C for up to 1000 h. The ultimate tensile strengths (UTSs) of four Al–Zr-Sc alloy wires reached 206–214 MPa, while the electrical conductivities were 57%–57.5% IACS. All four alloy wires were strengthened by a large number of Al3(Sc,Zr) nanoprecipitates. With the increase in Zr or Sc content, the UTS only slightly increased, which shows a low impact of the Zr and Sc levels on the tensile strength and electrical conductivity. Notably, remarkable reduction in tensile strength and change in the deformed grain structure were not observed for the four alloy wires during thermal exposure at 310 °C for up to 1000 h. After thermal exposure at 350 °C for 200 h, all four wires still exhibited excellent thermal stabilities. With prolonged exposures at 350 and 400 °C, the alloy wires became unstable. The high-Zr-content Al-0.18Zr-0.1Sc and Al-0.18Zr-0.15Sc alloys exhibited better thermal stabilities after long-term thermal exposures at 350 and 400 °C. This study on the thermal stability of Al–Zr-Sc conductor alloys under extreme conditions provides a valuable reference for industrial applications of thermally resistant Al conductor wires.
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来源期刊
Journal of Materials Research and Technology-Jmr&t
Journal of Materials Research and Technology-Jmr&t Materials Science-Metals and Alloys
CiteScore
8.80
自引率
9.40%
发文量
1877
审稿时长
35 days
期刊介绍: The Journal of Materials Research and Technology is a publication of ABM - Brazilian Metallurgical, Materials and Mining Association - and publishes four issues per year also with a free version online (www.jmrt.com.br). The journal provides an international medium for the publication of theoretical and experimental studies related to Metallurgy, Materials and Minerals research and technology. Appropriate submissions to the Journal of Materials Research and Technology should include scientific and/or engineering factors which affect processes and products in the Metallurgy, Materials and Mining areas.
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