高电势下混合层和交替层C/Cr包覆金属双极板对质子交换膜燃料电池的比较研究

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-04-15 Epub Date: 2025-01-25 DOI:10.1016/j.corsci.2025.112728
Yu-Fei Xie , Jia-Ming Liu , Qian Hu , Shuo Su , Xiuxin Zhang , Xiaopeng Lu , Hong-Qiang Fan , Xian-Zong Wang
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引用次数: 0

摘要

为了提高质子交换膜燃料电池双极板的耐久性,对混合层和交替层(混合c /Cr和替代c /Cr)两种涂层进行了比较评价。混合- c /Cr和alt-C/Cr的i0.84 V分别降至0.10和0.27 μA·cm−2,界面接触电阻分别为1.14和1.01 mΩ·cm2,满足DOE目标。分析表明,交替层防止了C层的分层,有利于形成多个界面,从而改善了界面电位分布。本研究的结果证实了混合层和交替层涂层策略在双极板上高性能涂层的前景。
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Comparative study of mixed- and alternating-layer C/Cr coated metal bipolar plates under high potentials toward proton exchange membrane fuel cells
To improve the durability of bipolar plates in proton exchange membrane fuel cells, two types of coatings with mixed- and alternating-layers (mix-C/Cr and alt-C/Cr) are comparatively evaluated. Both coating designing strategies meet DOE targets with i0.84 V declining to 0.10 and 0.27 μA·cm−2 and achieving low interfacial contact resistance of 1.14 and 1.01 mΩ·cm2 for mix-C/Cr and alt-C/Cr, respectively. Analysis suggests that alternating-layer prevent the delamination of C layer and contributes to multiple interfaces which polishing the interfacial potential distribution. The results of this study confirm the promise of mixed- and alternating-layer coating strategies for high-performance coatings on bipolar plates.
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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