Zr合金化对Ti-Zr合金在模拟HNO3热后处理条件下腐蚀行为的影响

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-04-15 Epub Date: 2025-01-23 DOI:10.1016/j.corsci.2025.112729
C.C. Liu , L.M. Zhang , Z. Liu , D.C. Ren , A.L. Ma , Z.X. Liu , Y.G. Zheng
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引用次数: 0

摘要

钛及其合金通过合金化增强了其耐腐蚀性,在高温HNO3特征的乏燃料后处理中显示出相当大的潜力。本研究采用实验研究与理论计算相结合的方法,研究了Zr合金化对Ti-Zr合金组织和腐蚀行为的影响。结果表明,Zr的加入增加了合金组织的无序性,从而提高了合金的力学性能。Zr的最佳添加水平显著提高了合金的耐腐蚀性和力学性能。这些发现强调了Ti-Zr合金在极端腐蚀性环境中的适用性,使其成为先进后处理应用的有希望的候选者。
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Influence of Zr alloying on the corrosion behavior of Ti-Zr alloys in simulated hot HNO3 reprocessing conditions
Titanium and its alloys show considerable potential for spent fuel reprocessing characterized by high-temperature HNO3 due to their enhanced corrosion resistance through alloying. This study investigated the effects of Zr alloying on the microstructure and corrosion behavior of Ti-Zr alloys, integrating experimental research with theoretical calculations. The results demonstrated that the addition of Zr increased microstructural disorder, which in turn improved the mechanical properties. Optimal levels of Zr significantly enhanced both the corrosion resistance and the mechanical properties of the alloys. These findings underscored the suitability of Ti-Zr alloys for extremely corrosive environments, making them promising candidates for advanced reprocessing applications.
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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