Co/ zn - mof衍生多孔碳材料作为吸附剂去除废水中的二甲胺四环素

IF 5.8 Q2 CHEMISTRY, MULTIDISCIPLINARY Results in Chemistry Pub Date : 2025-03-01 Epub Date: 2025-02-01 DOI:10.1016/j.rechem.2025.102094
Fuhua Wei , Peng Chen , Qinhui Ren , Qin Zhang , Wei Shang , Diaodiao Zhang , Min Li , Zhao Liang
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引用次数: 0

摘要

通过溶剂热法制备了Co/ zn - mof材料,并在900℃下进行了煅烧。采用扫描电镜(SEM)、傅里叶变换红外光谱(FT-IR)、x射线衍射(XRD)、氮吸附-脱附等温线等多种表征技术研究了其结构性质。这些分析旨在评估碳材料在二甲胺四环素去除效果方面的特点。实验结果表明,Co/ zn - mof制备的碳材料吸附二甲胺四环素的理想条件为:用量为20 mg,溶液浓度为50 ppm, pH值为10。此外,动力学研究表明,伪二阶模型能较好地反映实验数据。总之,本研究强调了Co/ zn - mof衍生的碳材料对米诺环素的显著吸附能力,表明了在环境净化方面的潜在应用,为环境保护提供了一种创新的方法。
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Removal of minocycline from wastewater via Co/Zn-MOFs -derived porous carbon materials as adsorbents
The Co/Zn-MOFs material was synthesized successfully via the solvothermal method and then underwent calcination at 900 °C. To investigate its structural properties, multiple characterization techniques were applied, such as scanning electron microscopy (SEM), Fourier-transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), and nitrogen adsorption-desorption isotherms. These analyses aimed to assess the features of the carbon material for its efficacy in minocycline removal. The experimental findings demonstrated that the ideal conditions for maximizing minocycline adsorption on the carbon material obtained from Co/Zn-MOFs comprised a dosage of 20 mg, a solution concentration of 50 ppm, and a pH level of 10. Furthermore, kinetic studies revealed that the pseudo-second-order model accurately represented the experimental data. In conclusion, this research underscores the remarkable adsorption capability of the carbon material derived from Co/Zn-MOFs for minocycline, indicating potential applications in environmental cleanup and presenting an innovative approach for environmental preservation.
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来源期刊
Results in Chemistry
Results in Chemistry Chemistry-Chemistry (all)
CiteScore
2.70
自引率
8.70%
发文量
380
审稿时长
56 days
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