水动力空化纳米气泡去除煤表面粘土涂层的效果及机理

IF 4.6 2区 工程技术 Q2 ENGINEERING, CHEMICAL Powder Technology Pub Date : 2025-04-15 Epub Date: 2025-02-08 DOI:10.1016/j.powtec.2025.120748
Bo Qiao , Zhongxian Wu , Ling Zhang , Shuo Yang , Dongping Tao
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摘要

煤颗粒表面的粘土包覆是导致浮选性能差的主要原因之一。它阻碍了浮选捕收剂在煤颗粒上的吸附和随后对气泡的附着,导致浮选恶化。研究了水动力空化纳米气泡对浮选过程中粘土包覆层的去除效果及机理。主要的表征和分析技术包括微浮选试验、分光光度计、聚焦光束反射测量(FBRM)、扫描电子显微镜(SEM)和纳米颗粒跟踪分析仪(NTA)。浮选试验表明,纳米气泡可使浮选回收率提高86.6%。纳米气泡显著减少了粘土涂层的不利影响,从而生产出更清洁的煤产品。当空化流量为1000 mL/min时,煤油吸附量几乎增加了一倍。原位FBRM粒度表征表明,煤浆经空化处理后,溶液中高岭石颗粒数量显著增加。同时,纳米泡浓度与溶液中的粒子数呈显著相关。结果表明,水动力空化和纳米气泡的联合作用能有效去除煤表面的粘土包覆层。
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Effects and mechanisms of clay coating removal from coal surface by hydrodynamic cavitation nanobubbles
The clay coating on coal particle surface is one of the main reasons for poor coal flotation performance. It hinders the adsorption of flotation collector on coal particles and their subsequent attachment to air bubbles, leading to deteriorated flotation. This study was aimed to explore the effects and mechanisms of clay coating removal in coal flotation by hydrodynamic cavitation nanobubbles. The main characterization and analysis techniques employed included micro-flotation tests, spectrophotometer, focused beam reflectance measurement (FBRM), scanning electron microscopy (SEM), nanoparticle tracking analyzer (NTA). The flotation tests showed that nanobubbles enhanced the flotation recovery by up to 86.6 %. Nanobubbles significantly reduced the adverse effects of clay coating and thus produced a cleaner coal product. The kerosene adsorption capacity was almost doubled at a cavitation flow rate of 1000 mL/min. The in-situ FBRM characterization of particle sizes showed that the number of kaolinite particles increased dramatically in solution following the cavitation treatment of coal slurry. Meanwhile, a significant correlation was identified between nanobubble concentration and particle number in the solution. These results showed that the combined effect of hydrodynamic cavitation and nanobubbles effectively removed the clay coating from coal surface.
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来源期刊
Powder Technology
Powder Technology 工程技术-工程:化工
CiteScore
9.90
自引率
15.40%
发文量
1047
审稿时长
46 days
期刊介绍: Powder Technology is an International Journal on the Science and Technology of Wet and Dry Particulate Systems. Powder Technology publishes papers on all aspects of the formation of particles and their characterisation and on the study of systems containing particulate solids. No limitation is imposed on the size of the particles, which may range from nanometre scale, as in pigments or aerosols, to that of mined or quarried materials. The following list of topics is not intended to be comprehensive, but rather to indicate typical subjects which fall within the scope of the journal's interests: Formation and synthesis of particles by precipitation and other methods. Modification of particles by agglomeration, coating, comminution and attrition. Characterisation of the size, shape, surface area, pore structure and strength of particles and agglomerates (including the origins and effects of inter particle forces). Packing, failure, flow and permeability of assemblies of particles. Particle-particle interactions and suspension rheology. Handling and processing operations such as slurry flow, fluidization, pneumatic conveying. Interactions between particles and their environment, including delivery of particulate products to the body. Applications of particle technology in production of pharmaceuticals, chemicals, foods, pigments, structural, and functional materials and in environmental and energy related matters. For materials-oriented contributions we are looking for articles revealing the effect of particle/powder characteristics (size, morphology and composition, in that order) on material performance or functionality and, ideally, comparison to any industrial standard.
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