耦合图格模拟相变过程:鲜奶油经鲜奶油加工成黄油过程中食品质地和品质的理论设计

IF 3.1 2区 化学 Q3 CHEMISTRY, PHYSICAL Journal of Chemical Physics Pub Date : 2025-02-14 DOI:10.1063/5.0251375
Erika Nozawa, Tetsuo Deguchi
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引用次数: 0

摘要

我们提出了一种理论模型,并模拟了鲜奶油在机械搅拌相变过程中自发或自组织出现的各种纹理图案的形成动力学。结果表明,该模型可用于鲜奶油和黄油产品的质地和质量设计。利用一种成熟的复杂系统方法——耦合映射晶格(CML),克服了从鲜奶油到生奶油再到黄油相变过程的建模复杂性。所提出的CML由一组最小的过程(即参数化的非线性映射)组成,如搅拌、聚结和絮凝,作用于适当的粗粒度场变量、表面能、内聚能和在二维方形晶格上定义的乳液的速度(流量)。在CML模拟中,在高温和低温下再现了两种众所周知的不同的相变过程。在这些过程中模拟的溢出和粘度变化至少在定性上与实验中观察到的一致。我们将这些表现出不同织构模式的过程描述为高搅拌温度下的粘度优势和低搅拌温度下的溢出优势,这是状态图之一。
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Simulating phase inversion processes by coupled map lattice: Toward the theoretical design of food texture and quality in dairy processing from fresh cream to butter via whipped cream.

We present a theoretical model and simulation for the formation dynamics of diverse texture patterns that emerge spontaneously or self-organize during phase inversion processes of fresh cream by mechanical whipping. The results suggest that the model should be applied for theoretically designing the texture and quality of whipped cream and butter products. The modeling complexity in phase inversion processes, from fresh cream via whipped cream to butter, was overcome by using a well-established complex systems approach, the coupled map lattice (CML). The proposed CML consists of a minimal set of procedures (i.e., parameterized nonlinear maps), such as whipping, coalescence, and flocculation, acting on the appropriately coarse-grained field variables, surface energy, cohesive energy, and velocity (flow) of the emulsion defined on a two-dimensional square lattice. In the CML simulations, two well-known and different phase inversion processes are reproduced at high and low whipping temperatures. The overrun and viscosity changes simulated in these processes are at least qualitatively consistent with those observed in experiments. We characterize these processes exhibiting different texture patterns as the viscosity dominance at high whipping temperatures and as the overrun dominance at low whipping temperatures on the viscosity-overrun plane, which is one of the state diagrams.

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来源期刊
Journal of Chemical Physics
Journal of Chemical Physics 物理-物理:原子、分子和化学物理
CiteScore
7.40
自引率
15.90%
发文量
1615
审稿时长
2 months
期刊介绍: The Journal of Chemical Physics publishes quantitative and rigorous science of long-lasting value in methods and applications of chemical physics. The Journal also publishes brief Communications of significant new findings, Perspectives on the latest advances in the field, and Special Topic issues. The Journal focuses on innovative research in experimental and theoretical areas of chemical physics, including spectroscopy, dynamics, kinetics, statistical mechanics, and quantum mechanics. In addition, topical areas such as polymers, soft matter, materials, surfaces/interfaces, and systems of biological relevance are of increasing importance. Topical coverage includes: Theoretical Methods and Algorithms Advanced Experimental Techniques Atoms, Molecules, and Clusters Liquids, Glasses, and Crystals Surfaces, Interfaces, and Materials Polymers and Soft Matter Biological Molecules and Networks.
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