{"title":"沸石咪唑酸骨架-14 （ZIF-14）水基合成新策略","authors":"Kiki Maesaroh , Ghefira Iftina Zahra , Apang Djafar Shieddieque , Muhamad Diki Permana , Irkham , Rudiawan Edwin , Joddy Arya Laksmono , Diana Rakhmawaty Eddy , Iman Rahayu","doi":"10.1016/j.rechem.2025.102097","DOIUrl":null,"url":null,"abstract":"<div><div>This study report outlines a water-based rapid method for synthesizing zeolitic-imidazolate framework-14 (ZIF-14) at room temperature. ZIF-14 crystals were prepared by the reaction of 2-eim, zinc nitrate, and cetyltrimethylammonium bromide (CTAB) in deionized water. The physicochemical analysis showed that ZIF-14 synthesized by this method has a coordination bond between Zn and N from FTIR analysis, which was also confirmed by XPS analysis. XRD analysis showed that the structure of ZIF-14 is a pure phase with analcime (ANA) topology. In addition, SEM and TEM images show that ZIF-14 has a cubic shape. In addition, thermal and surface analysis showed that ZIF-14 has a specific surface area of 429.518 m<sup>2</sup>/g, an average pore volume of 0.5676 cm<sup>3</sup>/g, and an average pore radius of 26.43 Å, with a thermal stability of up to 440 °C. Therefore, ZIF-14 synthesized by this method has a potential application as a catalyst and gas separation.</div></div>","PeriodicalId":420,"journal":{"name":"Results in Chemistry","volume":"14 ","pages":"Article 102097"},"PeriodicalIF":5.8000,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A novel strategy of water-based synthesis method of zeolitic-imidazolate framework-14 (ZIF-14)\",\"authors\":\"Kiki Maesaroh , Ghefira Iftina Zahra , Apang Djafar Shieddieque , Muhamad Diki Permana , Irkham , Rudiawan Edwin , Joddy Arya Laksmono , Diana Rakhmawaty Eddy , Iman Rahayu\",\"doi\":\"10.1016/j.rechem.2025.102097\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study report outlines a water-based rapid method for synthesizing zeolitic-imidazolate framework-14 (ZIF-14) at room temperature. ZIF-14 crystals were prepared by the reaction of 2-eim, zinc nitrate, and cetyltrimethylammonium bromide (CTAB) in deionized water. The physicochemical analysis showed that ZIF-14 synthesized by this method has a coordination bond between Zn and N from FTIR analysis, which was also confirmed by XPS analysis. XRD analysis showed that the structure of ZIF-14 is a pure phase with analcime (ANA) topology. In addition, SEM and TEM images show that ZIF-14 has a cubic shape. In addition, thermal and surface analysis showed that ZIF-14 has a specific surface area of 429.518 m<sup>2</sup>/g, an average pore volume of 0.5676 cm<sup>3</sup>/g, and an average pore radius of 26.43 Å, with a thermal stability of up to 440 °C. Therefore, ZIF-14 synthesized by this method has a potential application as a catalyst and gas separation.</div></div>\",\"PeriodicalId\":420,\"journal\":{\"name\":\"Results in Chemistry\",\"volume\":\"14 \",\"pages\":\"Article 102097\"},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2025-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Results in Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2211715625000803\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2025/2/7 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Results in Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2211715625000803","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/2/7 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
A novel strategy of water-based synthesis method of zeolitic-imidazolate framework-14 (ZIF-14)
This study report outlines a water-based rapid method for synthesizing zeolitic-imidazolate framework-14 (ZIF-14) at room temperature. ZIF-14 crystals were prepared by the reaction of 2-eim, zinc nitrate, and cetyltrimethylammonium bromide (CTAB) in deionized water. The physicochemical analysis showed that ZIF-14 synthesized by this method has a coordination bond between Zn and N from FTIR analysis, which was also confirmed by XPS analysis. XRD analysis showed that the structure of ZIF-14 is a pure phase with analcime (ANA) topology. In addition, SEM and TEM images show that ZIF-14 has a cubic shape. In addition, thermal and surface analysis showed that ZIF-14 has a specific surface area of 429.518 m2/g, an average pore volume of 0.5676 cm3/g, and an average pore radius of 26.43 Å, with a thermal stability of up to 440 °C. Therefore, ZIF-14 synthesized by this method has a potential application as a catalyst and gas separation.
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