矿物浸出对煤矸石燃烧效率的影响

IF 5.2 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Chemistry and Physics Pub Date : 2025-04-15 Epub Date: 2025-02-03 DOI:10.1016/j.matchemphys.2025.130482
Chen-hong Zhou, Hui-yong Niu, Hai-yan Wang, Yan-xiao Yang, Xiao-lu Liu
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引用次数: 0

摘要

水力侵蚀和风化破坏了暴露在自然环境中的煤矸石丘的内部完整性,加剧了氧化和自燃。选取热值高、挥发分高、自燃性好的七盘井煤矸石,在不同的浸泡条件下进行实验和加工。本工业分析考察了浸没条件如何影响煤矸石材料质量和燃烧。采用XRD和FTIR研究了浸渍后煤矸石中无机矿物和含有机碳官能团的变化。研究表明:浸水对煤矸石燃烧有促进作用,特别是在30%时。无机矿物浸出主要发生在浸出初期,浸出条件影响其浸出速率。浸泡15 ~ 30%时,煤矸石易氧化官能团(醇类、酚类、CO基团等)显著增加。浸泡法改善了煤矸石的组成和燃烧,为煤矸石的整体利用提供了新的思路。
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Effects of mineral leaching on combustion efficiency of coal gangue
Hydraulic erosion and weathering compromise the internal integrity of coal gangue hills exposed to the elements, exacerbating oxidation and spontaneous combustion. Select Qipanjing coal gangue with high calorific value, volatile matter, and self-igniting qualities for experimentation and processing under various soaking conditions. This industrial analysis examines how immersion conditions affect coal gangue material qualities and burning. The changes in inorganic minerals and organic carbon-containing functional groups in coal gangue following immersion are examined using XRD and FTIR. Studies show: Soaking improves coal gangue combustion, especially at 30 %. Inorganic minerals leach during the early soaking phase, and soaking conditions affect their leaching rate. At 15–30 % immersion, coal gangue's functional groups susceptible to oxidation (alcohols, phenols, CO groups, etc.) increased significantly. The soaking method improved coal gangue composition and combustion, providing new insights for its holistic use.
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来源期刊
Materials Chemistry and Physics
Materials Chemistry and Physics 工程技术-材料科学:综合
CiteScore
8.70
自引率
4.30%
发文量
1515
审稿时长
69 days
期刊介绍: Materials Chemistry and Physics is devoted to short communications, full-length research papers and feature articles on interrelationships among structure, properties, processing and performance of materials. The Editors welcome manuscripts on thin films, surface and interface science, materials degradation and reliability, metallurgy, semiconductors and optoelectronic materials, fine ceramics, magnetics, superconductors, specialty polymers, nano-materials and composite materials.
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